chemistry Flashcards

organic chemistry (50 cards)

1
Q

What organization has formulated general rules for nomenclature of organic compounds?

A

International Union of Pure and Applied Chemistry

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2
Q

How many essential parts should systematic names of chemicals contain?

A

4

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3
Q

What is the purpose of the prefix in the nomenclature of organic compounds?

A

To specify the location and identity of various substituent groups in the molecule

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4
Q

What does the locant specify in the nomenclature of organic compounds?

A

The location of the primary functional group

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5
Q

What is specified by the parent in the nomenclature of organic compounds?

A

The main part of the molecule with the number of carbon atoms

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6
Q

What is the role of the suffix in the nomenclature of organic compounds?

A

To specify the primary functional group

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7
Q

Which university has a virtual textbook on organic chemistry that can be followed to learn more?

A

Michigan State University

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8
Q
A
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9
Q

What is IUPAC Rule 1?

A

Finding the parent hydrocarbon

Subrule 1f: If there are two or more longest chains of equal length, the one having the largest number of substituents is chosen.

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10
Q

What does IUPAC Rule 2 focus on?

A

Numbering the carbon chain

Number the chain consecutively, starting at the end nearest a substituent group.

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11
Q

What is Subrule 2 of IUPAC Rule 2?

A

If both ends of the root chain have equidistant substituents:
* Begin numbering at the end nearest a third substituent, if one is present.
* Begin numbering at the end nearest the first cited group (alphabetical order).

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12
Q

What is IUPAC Rule 3 about?

A

Assigning the prefix and the locant

Designate the location of each substituent group by an appropriate number and name. Only alkyl groups are discussed for alkanes.

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13
Q

What does IUPAC Rule 4 entail?

A

Assembling the full name

Assemble the name, listing groups in alphabetical order using the full name. Two or more substituents are cited in alphabetical order.

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14
Q

What prefixes are not considered when alphabetizing substituents?

A

di, tri, tetra etc.

These prefixes are used to designate several groups of the same kind.

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15
Q

What punctuation is used to separate various prefixes in naming?

A

Hyphens

Commas are used to separate numbers.

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16
Q
A
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17
Q

What are the three essential features of an IUPAC name?

A
  1. A root or base indicating a major chain or ring of carbon atoms
  2. A suffix or other element(s) designating functional groups
  3. Names of substituent groups, other than hydrogen
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18
Q

Fill in the blank: An IUPAC name will have a root or base indicating a major chain or ring of _______.

A

[carbon atoms]

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19
Q

What does the suffix in an IUPAC name designate?

A

Functional groups that may be present in the compound

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20
Q

True or False: An IUPAC name includes only the names of carbon atoms in the molecular structure.

A

False

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21
Q

What is the role of substituent groups in an IUPAC name?

A

They complete the molecular structure and are other than hydrogen

22
Q

What are hydrocarbons having no double or triple bond functional groups classified as?

A

Alkanes or cycloalkanes

23
Q

What determines the classification of hydrocarbons as alkanes or cycloalkanes?

A

The arrangement of carbon atoms in chains or rings

24
Q

What is the significance of alkanes and cycloalkanes in organic chemistry?

A

They provide the framework for functional groups in other compounds and are ideal starting points for studying and naming organic compounds

25
What larger class of compounds do alkanes and cycloalkanes belong to?
Aliphatic compounds
26
What defines an aliphatic compound?
Compounds that do not incorporate any aromatic rings in their molecular structure
27
What suffix is commonly used to identify alkanes?
'ane'
28
List the IUPAC names for simple continuous-chain alkanes from C-1 to C-10.
* Methane * Ethane * Propane * Butane * Pentane * Hexane * Heptane * Octane * Nonane * Decane
29
Why should the names methane through decane be memorized?
They constitute the root of many IUPAC names
30
What is used in naming chains of five or more carbon atoms?
Common numerical prefixes
31
What is the formula structure increment for alkanes?
CH2 increment ## Footnote This indicates that each successive alkane differs from the previous one by a -CH2- unit.
32
What is a uniform variation in a series of compounds called?
Homologous ## Footnote This term describes compounds that have a similar structure but differ by a constant unit.
33
What rule do the formulas of alkanes fit?
CnH2n+2 ## Footnote This rule describes the relationship between the number of carbon (C) and hydrogen (H) atoms in alkanes.
34
What does the CnH2n+2 rule indicate about hydrogen to carbon ratio?
Highest possible H/C ratio for a stable hydrocarbon ## Footnote This means that alkanes are fully saturated with hydrogen.
35
What term is used to describe compounds with the maximum hydrogen to carbon ratio?
Saturated ## Footnote Saturated hydrocarbons contain the maximum number of hydrogen atoms per carbon atom.
36
What are cycloalkanes?
Cycloalkanes have one or more rings of carbon atoms.
37
What is the simplest example of cycloalkanes?
A single, unsubstituted carbon ring.
38
How do cycloalkanes relate to unbranched alkanes?
They form a homologous series similar to unbranched alkanes.
39
What is the general formula for a cycloalkane composed of n carbons?
CnH2n.
40
What happens when a simple unbranched alkane is converted to a cycloalkane?
Two hydrogen atoms must be lost, one from each end of the chain.
41
How does the hydrogen saturation of cycloalkanes compare to alkanes?
Cycloalkanes have two fewer hydrogens than the equivalent alkane but are still considered saturated.
42
True or False: Each carbon in a cycloalkane is bonded to four other atoms.
True.
43
Fill in the blank: The general formula for a cycloalkane is _______.
CnH2n
44
How are substituted cycloalkanes named?
In a fashion very similar to that used for naming branched alkanes
45
What is the chief difference in naming substituted cycloalkanes compared to branched alkanes?
The numbering system
46
Why does the numbering of cycloalkanes start at a substituted ring atom?
All the carbons of a ring are equivalent
47
True or False: A ring has ends like a chain does.
False
48
Fill in the blank: The numbering of substituted cycloalkanes starts at a _______.
[substituted ring atom]
49
what is rule number 1 for naming cycloalkanes?
For a no-substituted cycloalkane, the ring provides the root name, and the substituent is named as usual. No location number is needed.
50