chemistry Flashcards
organic chemistry (50 cards)
What organization has formulated general rules for nomenclature of organic compounds?
International Union of Pure and Applied Chemistry
How many essential parts should systematic names of chemicals contain?
4
What is the purpose of the prefix in the nomenclature of organic compounds?
To specify the location and identity of various substituent groups in the molecule
What does the locant specify in the nomenclature of organic compounds?
The location of the primary functional group
What is specified by the parent in the nomenclature of organic compounds?
The main part of the molecule with the number of carbon atoms
What is the role of the suffix in the nomenclature of organic compounds?
To specify the primary functional group
Which university has a virtual textbook on organic chemistry that can be followed to learn more?
Michigan State University
What is IUPAC Rule 1?
Finding the parent hydrocarbon
Subrule 1f: If there are two or more longest chains of equal length, the one having the largest number of substituents is chosen.
What does IUPAC Rule 2 focus on?
Numbering the carbon chain
Number the chain consecutively, starting at the end nearest a substituent group.
What is Subrule 2 of IUPAC Rule 2?
If both ends of the root chain have equidistant substituents:
* Begin numbering at the end nearest a third substituent, if one is present.
* Begin numbering at the end nearest the first cited group (alphabetical order).
What is IUPAC Rule 3 about?
Assigning the prefix and the locant
Designate the location of each substituent group by an appropriate number and name. Only alkyl groups are discussed for alkanes.
What does IUPAC Rule 4 entail?
Assembling the full name
Assemble the name, listing groups in alphabetical order using the full name. Two or more substituents are cited in alphabetical order.
What prefixes are not considered when alphabetizing substituents?
di, tri, tetra etc.
These prefixes are used to designate several groups of the same kind.
What punctuation is used to separate various prefixes in naming?
Hyphens
Commas are used to separate numbers.
What are the three essential features of an IUPAC name?
- A root or base indicating a major chain or ring of carbon atoms
- A suffix or other element(s) designating functional groups
- Names of substituent groups, other than hydrogen
Fill in the blank: An IUPAC name will have a root or base indicating a major chain or ring of _______.
[carbon atoms]
What does the suffix in an IUPAC name designate?
Functional groups that may be present in the compound
True or False: An IUPAC name includes only the names of carbon atoms in the molecular structure.
False
What is the role of substituent groups in an IUPAC name?
They complete the molecular structure and are other than hydrogen
What are hydrocarbons having no double or triple bond functional groups classified as?
Alkanes or cycloalkanes
What determines the classification of hydrocarbons as alkanes or cycloalkanes?
The arrangement of carbon atoms in chains or rings
What is the significance of alkanes and cycloalkanes in organic chemistry?
They provide the framework for functional groups in other compounds and are ideal starting points for studying and naming organic compounds