Chemistry Unit 5 Flashcards

1
Q

Describe the Bohr model

A

Nucleus orbited by electrons in different energy levels

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2
Q

When did the atomic model start?

A

in 400 BC

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3
Q

What did Democritus think

A

he believed that the atom was indivisible and the smallest piece of matter

named it “atomos” - not to be cut

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4
Q

Describe the billard ball model?

A

Just a ball like structure

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5
Q

Who created the billard ball model?

A

John dalton in 1804

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6
Q

What was the first atomic theory and who wrote it?

A

John Dalton wrote it

1) every element is made of atoms

2) he thought atoms of the same element are identical and different from other elements ** incorrect we have isotopes

3) In order to form compounds atoms of different elements combine in whole # ratios

4) In chemical reactions atoms are combine, separated, or rearranged but can never be turned into atoms of a different element

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7
Q

Describe the plum pudding model

A

Electrons scattered within a positively charged ball

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8
Q

Who created the plum pudding model and when

A

J.J Thomson in 1897

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9
Q

What did J.J thomson do and what was his atomic theory

A

JJ thomson experimented with cathode ray tubes and discovered the ELECTRON!

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10
Q

Describe the nuclear model

A

positively charged nucleus with negative electrons surrounding it

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11
Q

Who discovered the nuclear model and when?

A

Ernest Rutherford in 1911

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12
Q

What did Ernest Rutherford discover and how?

A

Through the gold foil experiment (bombarding alpha particles at a thin gold foil) he fouhnd that:

1) atom has mostly empty space
2) most of mass located in the positive NUCLEUS of the atom
3) electrons orbit around nucleus

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13
Q

describe the planetary model

A

Positive nucleus with protons and neutrons

electrons in specific energy levels can jump between them

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14
Q

Who created the planetary model and when?

A

niels bohr in 1913

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15
Q

What was niels bohr’s atomic theory

A

1) electrons exist in distinct orbits
2) electrons cant exist between energy levels
3) electrons can jump to higher orbit when energy is added
4) energy is released when electrons fall to lower orbit

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16
Q

Who discovered the neutron and when?

A

James Chadwick in 1932

17
Q

Who came up with the quantum mecanical model?

A

Schrodinger and heisenberg

18
Q

What was schrodinger’s atomic theory?

A

Wave mechanics – the idea that electrons are in clouds and not distinct orbitals

19
Q

What was heisenbergs atomic theory?

A

Uncertainty principle – electron location cant be predicted

electrons are both particles and waves

20
Q

Mass of the three sub atomic particles

A

P+ and N = mass of 1
E- = mass neglidgable

21
Q

What is the diamiter of an average atom?

A

10^-10 m

22
Q

what is the diamiter of an averge nucleus?

A

10^-15 m

23
Q

What is an isotope

A

They are atoms that have the same # of protons however the number of neutrons differs

24
Q

How does ratio of neutrons to protons affect nuclear stability

A

isotopes outside a certain ratio are considered radioactive

25
Q

how is mass and abundance of each isotope determined?

A

By using a mass spectrometer

26
Q

how is average mass # calculated?

A

(abundence/100 * Relative mass) +(abundence/100 * Relative mass) = average mass

27
Q

How is energy released when an electron moves from one energy level to the next?

A

In the form of light

28
Q

what does schrodinger’s equation determine?

A

the location of electrons in an atom

29
Q

Why does looking at an electron change its positiion

A

The act of looking at it alters its velocity and position

30
Q

What are the four quantum numbers?

A

n, l, ml, and m8

31
Q

What does the quantum number n describe?

A

Describes the shell (1-7)
The energy level
and the distance from nucleus

example the 1 in 1S shell

32
Q

what does l describe

A

Describes the subshell
- the shape and type of orbital
- 4 shapes: s, p, d, f
ex: the S in 1S

33
Q

what does ml describe

A

it describes the orbital
- the orientation in space and holds a max of 2 electrons

Ex: subshell S has 1 place for 2 electrons electrons and P has 3 places for 6 electrons

34
Q

what does m8 describe

A

describes the electron spin
either counter clockwise or clockwise

35
Q

What are the three Electron configuration rules?

A

1) pauli exclusion principle:
- no two e- in same atom can be describe by the same 4 quantum numbers

2) aufbau principle
- when filling orbitals the lowest energy orbitals are filled FIRST

3) Hunds rule
- whe orbitals of equal energy are filled the most stable is the one with the max number of unpaired electrons with the same spin

36
Q

what is ground state

A

it is the lowest energy of an electron

37
Q

what is an orbital?

A

it is the volume and shape of the place where an electron is likely found

38
Q

what does the term electron configuration mean?

A

it is the way that electrons are positioned outside the atom

39
Q
A