Chemsitry test Rate Of Reaction Flashcards
(20 cards)
Equation for calculating average rate
Rate = Change in amount of product/ time taken
OR
Rate = Change in amount of reactant/time taken
How does a chemical reaction occur?
there must be:
- enough energy greater to or equal to the activation rate for the reaction
- the reactants to collide
Activation Energy
It is the minimum amount of energy particles must possess if they are to react when they collide.
What is the rate of reaction?
The rate of a reaction is a measure of the number of successful collisions per unit time.
What does the gradient tell us?
The steeper the gradient the faster the rate of reaction
How does the gradient typically change during a reaction?
It starts off steep than the gradient decreases until the graph plateaus and the reaction stops.
Describe collusion theory
Collision theory states that in order for a chemical reaction to occur there must be energy greater or equal to the activation energy and the reactants must collide.
Activation Energy
The minimum amount of energy, particles must possess of for them to react when they collide.
Why does the rate of reaction decrease during the reaction?
As there are fewer reactants particles, there are fewer collisions between reactant per unit time and therefore fewer successful collisions per unit time.
How does surface area affect the rate of reaction?
- The smaller the pieces of solid reactant, the faster the rafters of reaction.
- Smaller pieces have a larger surface area than larger pieces with the same total mass.
- More particles of the solids reactant are in contact with particles of the other reactant
- Therefore there are more collisions between reactant particles per unit time, so the rate of reaction increases.
How does concentration affect the rate of reaction?
- Increasing the concentration of a reactant in solution means that there are more particles of that reactant in a given volume.
- Therefore there are more successful collisions between reactant particles per unit time.
- the rate of reaction increases.
How does temperature affect the rate of reaction?
1.The higher the temperature the faster the rate of reaction
2. At a higher temperature, reactant particles have more kinetic energy and so move around faster.
3. This results in more collisions per unit time between reactant particles.
4. As well, more particles will collide with energy equal to or greater than the activation energy, so more of the collision will be successful.
How does pressure affect the rate of reaction?
Increasing the pressure means that there are more reactants particles particles in a given volume.
As a result, there are more collisions between reactant particles per unit time, so the rate of reaction increases.
How do catalysts affect the rate of reaction?
Catalysts provide an alternative reaction pathway with a lower activation energy.
This means that more collisions will have energy equal to or greater than the activation energy, so more of the collisions will be successful.
What are catalysts?
A catalyst is a substance that speeds up the rate of a reaction but is chemically unchanged at the end. It is not used up in the reaction.
Marble Chips Experiment Method
- Set up the apparatus and clamp the gas syringe in place.
- Measure the hydrochloric acid into the conical flask and add the marble chips to the conical flask
- Quickly replace the bung and start a timer. Swirl frequently.
- Record the time taken for 50cm3 of gas to be produced.
- Repeat the experiment with the same marble chips but different concentrations of acid.
Word equation for marble chips reaction (surface area)
Calcium carbonate + hydrochloric acid —> calcium chloride + water + carbon dioxide.
Symbol equation for marble chips reaction
CaCO3 + 2HCl —> CaCl2 + H2O + CO2
Method for Marbel chips experiment (surface area)
- Place a measuring cylinder upside down in the water trough. The measuring cylinder should be completely full of water.
- Clamp the measuring cylinder in place.
- Measure the hydrochloric acid into the conical flask.
- Add large ,arable chips to the conical flask, quickly replace the bung and starter the timer.
- Swirl well and record the volume of gas produced every 10 seconds.
Why is the mixture cloudy?
The chemical reaction is producing sulfur which is precipitate and turns the mixture cloudy when produced.