Chpt 10 and 11 Flashcards

(41 cards)

1
Q

describe dispersion forces (or london forces)

A
  • they are super weak
  • temporary dipoles
  • all atoms, ions and molecules
  • high MW, stronger attractions
  • shape could matter
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2
Q

describe dipole-dipole attractions

A
  • results of permanent dipole
  • it depends if there is polar or non-polar compound
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3
Q

describe hydrogen bonding

A
  • its a really strong type of dip-dip
  • occurs only for HF, HO, or HN
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4
Q

ion-dipole reactions

A
  • reason most ionic compds dissolve in water
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5
Q

definition: ability of two liquids to mix (and not separate into layers)
- polar w/polar
- nonpolar w/nonpolar

A

miscibility

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6
Q

definition: sticks to other things

A

adhesive

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7
Q

definition: sticks together

A

sticks together

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8
Q

What attractions happen with mercury in a glass

A

cohesive properties

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9
Q

What attractions happen with water in a glass

A

adhesive properties

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10
Q

What happens with surface tensions

A

the molecules on the surface are attracted inward and form a skin on the surface

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11
Q

In surface tensions as IMF become higher what happens

A

the surface tensions becomes stronger

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12
Q

in surface tensions as temperature rises what happens

A

it become weaker…the molecules are moving quicker

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13
Q

definition: measure of resistance to flow

A

viscosity

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14
Q

What is the trend for viscosity when IMF or Temp rises?

A

When IMF increases viscosity increases and when temp increases viscosity decreases

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15
Q

definition: flow up a tub(against gravity)

A

capillary action

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16
Q

vaporization is what phase change

A

liquid to gas

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17
Q

condensation is what phase change

A

gas to liquiz

18
Q

As IMF increases what happens to the rate of vaporization?

A

It is increases and is harder to vaporize

19
Q

What is happenig in Le Chatlier’s Principle

A

liquid + heat energy –><– vapor(double arrow)

20
Q

In Le Chatlier’s Principle what would happen if you add heat

A

it would shift to the right and there would be more vapor

21
Q

In Le Chatlier’s Principle what would happen if you cool it?

A

It would shift to the left and add more liquid

22
Q

What are the trends for vapor pressure

A
  • As IMF is greater VP decreases
  • As Temp increases VP will increases
23
Q

What is the definition of vapor pressure

A

pressure of vapor of a liquid in equilibria w/ liquid phase in a closed container

24
Q

what is the definition of boiling points

A

The temp at which v.p. of a liquid = the applied pressure

25
boiling point trends
- As IMF is greater BP will increase - As external P greater BP will increase
26
sublimation is what phase change?
solid --> gas
27
deposition is what phase change?
gas --> solid
28
definition: amount of heat required to raise the temp of 1 gram of substance by 1C
specific heat
29
What is melting points definition
the temp that the rate of melting is the same as the rate of freezing
30
definition: amount of heat required to convert 1g solid to liquid @ mp
heat of fusion
31
definition: amt of heat required to convert 1g liquid to vapor @ b.p.
heat of vaporization
32
What is the equation for specific heat?
mass * specific heat * change in temperature
33
these are characteristics of which solids? - strong ion-ion interactions - high m.p. and b.p. - solids @ room temp - dissociate in water - hard & brittle - dont conduct electricity
ionic solids
34
These are the characteristics of which type of solids - hard - malleable & ductile - conduct electricity & heat as solids and liquids - usually very dense - range of mp
metallic solids
35
these are characteristics of which solids - high mp - very hard and brittle - most do not conduct electricity - undending network of covalent bonds
covalent network solids
36
these are characteristics of which type of solids - low mp - soft - poor conductor of heat and energy - frozen molecule cmpds
molecular solids
37
an examples of a molecular solid is what?
H2O(s)
38
an example of a covalent network solid is what?
diamond
39
What are the different forms of carbon
- graphite (sp2) - diamond (sp3) - fullerenes(sp2) - nanotubes(sp2)
40
definition: different bonding modes
allotropes
41