Class6 Flashcards

(31 cards)

1
Q

The difference between aldehydes and ketones

A

Is the placement of the carbonyl group
Aldehyde- C–O at the end
Ketone- C–O in the middle

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2
Q

Methanal (formaldehyde)

A

H- C -H
||
O

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3
Q

Ethanal (acetaldehyde)

A

H3C- C - H
||
O

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4
Q

Pentanal (Valeraldehyde)

A

CH3-CH2-CH2-CH2- C -H
||
O

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5
Q

Propanone(acetone)

A

CH3- C - CH3
||
O

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6
Q

Acetophenone

A

.

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7
Q

Benzophenone

A

.

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8
Q

Important aldeyhyde
Methanal
Ethanal
2,3-dihydroxypropanal
Benzaldehyde

A

Formaldehyde
Acetaldehyde
Glyceraldehyde
-

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9
Q

Important ketones
Propanone
1,3-dihydroxypropanone

A

Dimethyl ketone= acetone
Dihydroxyacetone

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10
Q

Oxidation reaction for
Primary alcohols->
Sec. Alcohols->

A

Aldehyde-> carboxylic acid
Ketone-> no more oxidization

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11
Q

Reduction rection for
Aldehyde->
Ketone->

A

Primary alcohol
Secondary alcohol

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12
Q

Addition of water to carbonyl compounds forms

A

Hydrate

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13
Q

Addition of alcohols to carbonyl acids forms

A

Hemiacetal or hemiketal

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14
Q

Addition of nitrogen to carbonyl compounds forms

A

Imine

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15
Q

Oxidation agents to produce aldehydes or ketones

A

Acidified potassium dichromate K2Cr2O7 orange to green
Acidified potassium manganate KMnO4 purple to colorless

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16
Q

Aldehydes and ketones can be reduced by reducing agents such as

A

NaBH4 or LiAlH4

17
Q

Aldehydes are reduced to…
Ketones are reduced to…

A

Primary alcohols
Secondary alcohols

18
Q

………..is a reaction where a nucleophile (electron-rich species) reacts with an electron-deficient center, typically a positively polarized carbon atom in a molecule. In the context of carbonyl compounds like aldehydes or ketones, nucleophilic addition involves the attack of a nucleophile on the carbon atom of the carbonyl group.

A

Nucleophilic rxn

19
Q

Carboxyl group

A

R-COOH /R-CO2H

20
Q

Suffixes for carboxylic aids

A

-oic / -dioic acid

21
Q

Widely distributed in nature
Tart taste (vinegar, sour milk)
Weak acids

A

Carboxylic acids

22
Q

Oxalic acid
Malonic acid
Succinic acid
Glutaric acid
Adipic acid

A

HOOC-COOH
HCOOC-CH2-COOH
HOOC-(CH2)2- COOH
HOOC-(CH2)3-COOH
HOOC-(CH2)4-COOH

23
Q

Benzoic acid(benzene carboxylic acid) draw

24
Q

Salicylic acid( 2-hydroxybenzoic acid) draw

25
Phtalic acid draw
.
26
Carboxylic acid table red squares
.
27
Oxidation of primary alcohols and aldehydes lead to
Production of carboxylic acids
28
Hydrolysis of nitriles using either dilute acid or dilute alkali followed by acidification forms
Carboxylic acids
29
Hydrolysis of esters by dilute acid or dilute alkali and heat followed by acidification forms
Carboxylic acid and alcohol
30
The condensation rxn between an alcohol and carboxylic acid forms
Esters
31
Reactions of carboxylic acids
Redox rxn with reactive metals producing salt and hydrogen gas Acid-base rxns with carbonates producing salt+water+co2 Reduction by LiAlH4 producing primary alc+ water Neutralisation rxns with alkalis producing salt+water Esterification with alcs and H2SO4 as catalyst producing ester+ water