composite Flashcards
composition of comp
1 glass filler particles
2 resin
3 camphorquinon
4 low weight dimetharcylate
5 silane coupling agent
sizes of filler particles
conventional 10-40um
fine
microfine extremely small about 0.04um
hybrid most common
common resin
BIS GMA = bisphenol and glycidyl methacrylate
urethane dimethacrylate
chemical structure of resins
c=c
difunctional molecules
what sort of reaction does comp undergo
resin facilitate crosslinking when double bonds are activated by light
free radical addition polymerisation
blue light wavelength
430-490nm
do all resin monomers react?
only 30-80%
what happens when resin is light cured and undergoes additon polymerisation
resin increases in molecular weight and viscosity and strength
function of Low weight dimethacrylate
adjust viscosity and reactivity
adjust rate of polymerisation
function of Silane coupling agent
allow intimate contact between filler and resin
normally water adheres to glass filler particle preventing resin from boding to surface
is glass filler or resin stronger and harder
glass filler
which filler type has the highest filler load
hybrid
Effect of adding filler particles
o improved mechanical properties
o improves strength
o rigidity
o hardness
o abrasion resistance
o lower thermal expansion
o lower polymerisation shrinkage because less resin as a % of volume
o less exothermic
o improved aesthetics
types of Curing method of comp
self cure 2 paste
light cure 1 paste
posterior restoration use what type of filler particle comp
heavly filled
anterior restoration use what type of filler particle comp
microfine or submicron hybrid
Advantages of light curing
- extended working time
- short setting time
- higher filler levels than 2 paste
- less porosity than 2 paste
- less bubbles, voids which makes the material weaker
Disadvantages of light curing
- premature polymerisation
- overly optimistic depth of cure
- retinal damage
- exothermic rxn might damage pulp and soft tissues
- polymerisation shrinkage -> debond -> microleakage
- If you use increments that is >2mm, soggy bottom, underpolymerised base, wont bond to underlying tooth fully
recommended setting time
> 30s
Differing definitions of DoC
Old ISO4049 definition:
Height of the residual fully cured composite divided by 2
New definition:
DoC is defined as the depth at which the material hardness is about 80%-90% that of the cured surface
DoC definition
Which is defined as the layer thickness you can apply while ensuring the composite is cured adequately
DoC values
- 2mm for hybrid comp
- up to 6mm for bulk fill comp but usually 4mm
What is bulk fill?
- can place larger increments in bulk
what light source for bulk
polywave