core practical 11: redox titrations Flashcards

(9 cards)

1
Q

usual reactants

A

fe 2+ awith mno4 -

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2
Q

why is no indicator needed?

A

self indicating due to colour change of the manganate

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3
Q

mno4- is

A

purple

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4
Q

mn2+ is

A

(pale pink)
colourless

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5
Q

why do u need an acid

A

to provide h+ for mno4- to mn2+

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6
Q

what acid to use

A
  • dilute sulfuric acid
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7
Q

if insufficient volume of acid used, or a weak acid like ethanoic acid?

A
  • mno4- is only reduced to mno2 INSTEAD of mn2+
  • which is brown, so masks the colour change
  • so larger volume of manganate would be used
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8
Q

why not use HCl?

A
  • mno4 - would OXIDISE the cl- to cl2
  • ref the e cell
  • greater titre
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9
Q

why not use hno3

A
  • would oxidise fe2+ to fe 3+
  • reference e cell
  • SMALLER TITRE
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