Covalent bonding - HL Flashcards

(49 cards)

1
Q

What do the delocalised electrons do in a resonance structure ?

A

The delocalised electrons are spread evenly across the bonding positions where the double bond can be found

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

How would you know if someone would display resonance ?

A

If there is more than one place for a double or triple bond , then the molecules can display resonance

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What physical evidence suppprts the resonance structure of benzene

A

All carbon-carbon bonds are of equal length with equal binding angle of 120

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Define bond energy

A

The bond energy is required to break one mole of a particular covalent bond in the gaseous state

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Triple bonds are the

A

shortest and strongest
due to large lecturing density

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Single covalent bonds are

A

longest and weakest

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

2 ED 0 LP

A

linear

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

3ED 0LP

A

Trigonal Planar

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

lone pairs reduce

A

bond angle

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

4 ED 0LP

A

Tetrahedral

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

3BP 1 LP

A

trigonal pyramidal

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

2 BP 2LP

A

bent

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

2BP 1LP

A

Bent

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

what bond angle is linear

A

180

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

what bond angle is trigonal planar

A

120

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

what bond angle is tetrahedral

A

109.5

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

Shape of 5BP 0LP

A

Trigonal Bipyramidal

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

Shape of 4BP 1LP

A

See-saw

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

Shape of 3BP 2LP

A

T-shaped

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

Shape of 2BP 3LP

21
Q

Shape of 6BP 0LP

22
Q

Shape of 5BP 1LP

A

Square Pyramidal

23
Q

Shape of 4BP 2 LP

A

Square Planar

24
Q

Shape of 3BP 3 LP

25
Shape of 2BP 4LP
bent
26
what is a dipole
measure of how polar a bond is
27
When a diatonic molecule e.g cl2 the electronegativity is shrared equally therefore the covalent bond is
non-polar
28
When two atoms in a covalent bond have different electronegativities what is the covalent bond
polar
29
the bigger the difference in electro negativity the
higher the polarity of the covalent bond
30
the dipole arrow points to the
partially negative charged end
31
What needs to be taken into consideration when a molecule has more than two atoms when deciding the polarity
• The polarity of each bond within the molecule • How the bonds are arranged in the molecule
32
when the pull of the atoms are not equal and opposite there is a net pull so
the molecule is polar
33
what is the formula of silicon oxide
Si02
34
Why do giant covalent lattice have high melting and boiling points
large number of covalent bonds , a lot of energy is required to break the lattice
35
6 examples of giant covalent structures
diamond , graphite , graphene , buckminsterfullerene , silicon , silicon dioxide
36
what are the three type of intermolecular forces
London dispersion forces Dipole-dipole attraction hydrogen bonding
37
London forces are
present between all atoms and molecules
38
The strength of the london dispersion forces depends on two factors
number of electrons in the molecule surface area of the molecules
39
The greater the number of electrons in the molecule the
stronger the dispersion forces and melting/boiling points are stronger
40
What is the strongest intermolecular force
Hydrogen bonding
41
For hydrogen bonding to take place it needs a species which has
(F,O,N) with an available lone pair of electrons
42
How to work out RF value
distance travelled by component/ distance travelled by solvent
43
What is the equation for formal charge
FC = (number of valence electrons) - 1/2(number of bonding electrons) - (number of non-bonding electrons) FC = V - 1/2B-N
44
the lewis formal which is preferred is the FC
closest to 0
45
How is a sigma bond formed
the head on overlap (axial or end to end) of atomic orbitals (s-s) (s-p) (p-p)
46
How is a pi bond formed
by sideways overlap of atomic orbitals
47
how many sigma and pi bonds in a single covalent
1 sigma 0 pi
48
how many sigma and pi bonds in a double covalent bond
1 sigma 1 pi
49
how many sigma and pi bonds in a triple covalent bond
1 sigma 2 pi