DAT Gen Chem Atomic and Molecular structure Flashcards

1
Q

are closest to
the positively charged nucleus.

A

core electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

which electrons are the most stable and are lowest in energy.

A

core electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Changing the number of neutrons of an atom, leaving protons the same

A

isotope

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

what produces ions

A

changing the number of electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

elements within a compound always combine in
a fixed proportion.

A

law of constant composition

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

the molecules undergo
rearrangement to produce a physical change.

A

physical reaction

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

involve
the substances undergoing a chemical change
whereby a new substance is created.

A

chemical reaction

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

when two or
more atoms or molecules combine to form
a single compound.

A

synthesis rxn

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

when a
compound breaks down into two or more
products.

A

decomposition rxn

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

when
one element is replaced by another in a
compound.

A

single displacement rxn

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

exchange
of bonds between two reacting chemical
species.

A

double displacement rxn

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

common types of double displacement

A

neutralization
and precipitation reactions.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

when a
substance reacts with O2 gas to produce
light and heat.

A

conbustion

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Represents the main energy level
occupied by electrons.

A

principle quantum number

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Is a positive integer, greater than or
equal to 1.

A

principle quantum number (n)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

maximum number of electrons
that an electron shell can hold is
given by the formula:

A

2n squared

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

Describes the shape of the subshells
or the orbital shape within each
principal energy level

A

Azimuthal Quantum Number (l)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

possible values of the azimuthal
quantum number

A

all integers between 0 and n-1

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

l=0

A

s subshell

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

l=1

A

p subshell

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

l=2

A

d subshell

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
22
Q

l=3

A

f subshell

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
23
Q

how many e can s sub shell hold

A

2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
24
Q

how many e can p sub shell hold

A

6

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
25
how many e can d sub shell hold
10
26
how many e can f sub shell hold
14
27
which orbital is spherical
s
28
which orbital is shaped like dumbbells
p
29
Describes the orientation of orbitals in space.
Magnetic Quantum Number (ml)
30
The magnetic quantum number ranges between
the negative and positive magnitude of the azimuthal quantum number.
31
Describes the angular momentum of an electron.
Spin Quantum Number (ms)
32
Spin Quantum Number (ms) denoted as either
+1/2 or -1/2
33
states that no two electrons in an atom can have the exact same set of four quantum numbers.
Pauli’s Exclusion Principle
34
s sub shell has how many orbitals
1
35
p sub shell has how many orbitals
3
36
d sub shell has how many orbitals
5
37
f subshell has how many orbitals
7ho
38
how many e per orbital
2
39
4s subshell gets filled BEFORE
3d bc its lower in energy
40
When two species have the same electron configuration, it means that they have the same arrangement of electrons. They are known as
isoelectronic species
41
formed between two atoms with significantly different electronegativities. (metals and nonmetals)
ionic bond
42
involve the complete transfer of electrons from the less electronegative atom to the more electronegative atom.
ionic bond
43
crystalline structures are found in what kind of bond
ionic
44
very high melting and boiling points are characteristics of what bond
ionic
45
soluble in water, where they dissociate into cations and anions. translate to what bodn
ionic
46
conduct electricity when dissolved in aqueous solutions or when they are melted.
ionic compound
47
bonds formed between two atoms that have similar electronegativities. (nonmetal-nonmetal)
covalent bond
48
do covalent bonds share e
yes
49
which e do covalent bonds share
valence
50
have lower melting and boiling points. what bond
covalent
51
are covalent bonds soluble or insoluable
insoluable
52
do covalent bonds conduct electricity
no
53
describes the distance between the nuclei of each atom involved in the bond.
bond length
54
describes the energy needed to break a covalent bond.
bond energy
55
have their atoms covalently bonded into a network. These atoms are held together very tightly, even tighter than most other covalent compounds!
covalent network solids
56
utilize a type of covalent bonding whereby both electrons involved in the bond come from the same atom.
Coordinate covalent compounds
57
utilize a type of covalent bonding whereby both electrons involved in the bond come from the same atom.
Coordinate covalent compounds
58
occurs between metal atoms.
metallic nond
59
A metallic bond arises from the
electrostatic force between the delocalized electrons and positively charged metal ions.
60
excellent conductors of electricity.. what bond?
metallic bond
61
ductile... what bond?
metallic
62
malleable... what bond
metallic
63
lustrous, or shiny.... what bond
metallic
64
The forces that form covalent or ionic bonds are termed as
intramolecular forces
65
the forces found between molecules.
intermolecular forces
66
the weakest intermolecular interactions.
London Dispersion / Van der Waals forces
67
occurs when the electron density between two atoms becomes unevenly distributed for a brief time resulting in an instantaneous dipole.
London Dispersion / Van der Waals forces
68
All compounds experience the
LDF
69
London Dispersion forces get larger as the size of the molecule
increass
70
occurs when the partially positive side of a molecule attracts the partially negative side of another molecule.
dipole dipole forces
71
interaction is only found in polar solid and liquid compounds
dipole dipole
72
strong dipole-dipole interactions that occur when hydrogen is attached to highly electronegative nitrogen, oxygen, or fluorine atoms.
hydrogen bonds
73
what elements are involved in hydrogen bonds
nitrogen, oxygen, flourine
74
stronger than other dipole-dipole interactions.
hydrogen bonding force
75
describe the attraction between an ion and polar molecule.
ion dipole interactions
76
increasing the strength of intermolecular forces implies that these molecules are held...
more tightly together
77
does Increasing Intermolecular Forces increase or decrease vapor pressure
decrease
78
does Increasing Intermolecular Forces increase or decrease melting and boiling pts
increase
79
does Increasing Intermolecular Forces inc or dec viscocity
increasedoes
80
does Increasing Intermolecular Forces inc or dec surface tension
increase
81
illustrates that bonding between two atoms occurs due to the overlap of their atomic orbitals.
molecular orbital theory
82
Species that have unpaired electrons and are attracted to a magnetic field are known as
paramagnetic
83
single bond has a bond order of what
1
84
triple bond has bond order of what
3
85
when a central atom is surrounded by 3 electron domains, the atoms arrange themselves to be 120° apart from each other.
trigonal planar
86
when a central atom is surrounded by 5 electron domains, the atoms arrange themselves to form this 3-dimensional shape
trig bipyrimidal
87
when an atom forms four bonds, it assumes a...
tetrahedral geometry