DAT Gen Chem Solutions Flashcards

(52 cards)

1
Q

has less than the maximum amount of solute
dissolved in a solvent.

A

unsaturated soln

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2
Q

maximum amount of
solute dissolved in a solvent.

A

saturated soln

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3
Q

contain even more dissolved solute than
they can normally hold at a given temperature
and pressure.

A

supersaturated soln

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4
Q

when a dissolved solute
comes out of the solution.

A

crystalization

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5
Q

These crystals are
generally formed by

A

manipulating temp or pressure

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6
Q

Group 1 metal cations, what kind of salt

A

soluble salt

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7
Q

Ag+, what kind of salt

A

insoluble salt

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8
Q

No3- what kind of salt

A

soluable

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9
Q

ClO4- what kind of salt

A

solable

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10
Q

C2H3O2- what kind of salt

A

soluble

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11
Q

NH4+, what kind of salt

A

soluble

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12
Q

Pb2+, Hg2+ what kinda salt

A

insoluble

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13
Q

Oh- what kinda salt

A

insoluble

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14
Q

S2- what kinda salt

A

insoluble

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15
Q

CO3 2-, PO4 2-

A

insoluble

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16
Q

soluble component generally

A

trumps insoluble component

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17
Q

HCl, HBr, HI, HClO4, HClO3,
H2SO4, HNO3.

A

strong acids

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18
Q

Group I Metal Hydroxides,
Ca(OH)2, Sr(OH)2, Ba(OH)2.

A

strong bases

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19
Q

HF, HCN, CH3COOH, etc.

A

weak acids

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20
Q

NH3, CH3NH2, etc.

A

weak bases

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21
Q

Solids are more soluble at what temps

22
Q

Gases are more soluble at what temps

23
Q

Gases are more soluble at what pressures

24
Q

For solids in liquids, an “blank” in tempting solubilty

25
method that measures how much a chemical substance absorbs light by measuring the intensity of light as a beam of light passes through a sample solution.
spectrophotometry
26
following formula illustrates Beer’s law: (absorbance)
absorbance = molar absorptivity x path length x conc of soln
27
unit for molar absorptivity
M-1*cm-1
28
are the attractive and repulsive forces between separate molecules.
intermolecular forces
29
arise from the temporary attraction between adjacent atoms or molecules.
LDF
30
dilution formula
m1v1=m2v2
31
concentration in terms of the equivalents of one chemical species that reacts stoichiometrically with another chemical species.
normality (N)
32
Normality eqn
N=number of equivalents x molarity
33
ratio of the number of moles of one component of a mixture to the total number of moles.
mole fraction (X)
34
mole fraction of solute =
moles of solute/total moles in soln
35
depend upon the concentration of solute molecules or ions, but not upon the identity of the solute itself.
colligative properties
36
depend on the identity of the dissolved species and solvent.
noncolligative properties
37
property of a liquid that allows it to resist an external force due to the cohesive nature of its molecules.
surface tension
38
is surface tension colligative or non colligative
non colligative
39
the attractive forces between molecules of the same substance,
cohesive
40
attractive forces between molecules of different substances.
adhesive forces
41
measure of a fluid’s resistance to flow.
viscocity
42
is viscosity a colligative or non colligative property
non colligative
43
are color and density colligative or non colligative
non colligativeis
44
is solubility colligative or non colligative
non colligative
45
which is the point where the vapor pressure equals the atmospheric pressure.
boiling pti
46
is boiling pt colligative or non colligative
colligative
47
as vapor pressure increases, boiling point....
decreases
48
The vapor pressure of a pure solvent is... than the vapor pressure of a solution containing non-volatile solutes.
greater than
49
calculate the new vapor pressure after a solute has been added, use Raoult’s law:
VP of soln after solute has been added = mole fraction x pure VP
50
change in boiling point temperature can be calculated using the following formula:
change in temp = solvents BP elev constant x solute vant hoff factor x molality
51
The change in freezing point temperature can be calculated using the following formula:
change in temp = - FP depression constant x vant hoff factor x molality
52
The osmotic pressure can be calculated using the following formula:
osmotic pressure = vant hoff factor x molarity x universal gas constant x temp (K)