definitions Flashcards
(17 cards)
features of homologous series
-same general formula
-similar chemical properties
-trend in physical properties
-each differs from the next by CH2
general formula
shows number of atoms of each element in a compound with n carbon atoms
molecular formula
shows actual number of atoms of each element in a compound
empirical formula
shows simplest whole number ratio of atoms of each element in a compound
structural isomerism
same molecular formula but different structural formula
stereoisomerism
same structural formula but bonds are arranged differently in space
cracking
breaking of longer-chain alkanes into smaller ones
free radical
reactive species due to presence of unpaired electron
E isomer
higher priority groups attached to each C are on oppositE sides of double bond
Z isomer
higher priority groups attached to each C are on the same side of the double bond
major product
forms from the most stable carbocation
addition polymerisation
large number of monomers join to form an unreactive polymer
molecular ion (for electron impact ionisation)
molecule with an electron knocked off
molecular ion (for electrospray ionisation)
molecule with a H⁺
fingerprint region
area below 1500cm⁻¹ which is unique for any substance and can be used to identify a compound by looking for an exact match in an online database
condensation reaction
two molecules join together, involving elimination of a small molecules