Definitions Flashcards

1
Q

Isotopes

A

Atoms of the same element that have a different number of neutrons

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2
Q

Relative isotopic mass

A

Mass of an atom of an isotope compared to 1/12 the mass of an atom of carbon-12

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3
Q

Relative atomic mass

A

Weighted mean mass of an atom compared to 1/12 the mass of an atom of carbon-12

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4
Q

Mole

A

Amount of any substance that has the same number of particles as exactly 12g of carbon-12

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5
Q

Molar mass

A

Mass of 1 mol of substance

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6
Q

Salt

A

Chemical compound formed when the H ion of an acid is replaced with a metal or ammonium ion

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7
Q

Hydrated

A

Contains waters of crystallisation

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8
Q

Water of crystallisation

A

Water molecules in an ionic lattice

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9
Q

Acid

A

Proton donor

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10
Q

Base

A

Proton acceptor

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11
Q

Alkali

A

Soluable base

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12
Q

Disproportionation

A

A reaction where the same element both oxidises and reduces

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13
Q

1st Ionisation energy

A

Energy required to remove one mole of electrons from one mole of gaseous atoms to form one mole of +1 gaseous ions

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14
Q

Orbital

A

A region of space which can take a max of 2 electrons with paired opposing spins

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15
Q

Isoelectric

A

Same electron arrangement but different elements

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16
Q

Covalent bonding

A

The electrostatic attract between the positive nuclei of one atom and a pair of shared electrons

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17
Q

Dative covalent bond

A

When one atom supplies both electrons for the bond

18
Q

Ionic bonding

A

The electrostatic attraction between oppositely charged ions

19
Q

Electronegativity

A

The ability of an element to attract a pair of electrons from a bond

20
Q

Periodicity

A

A property that has a pattern across a period that is repeated across successive periods

21
Q

Giant structure

A

Has no fixed size so can continuously add atoms to the same structure

22
Q

Average bond enthalpy

A

Energy required to break one mole of bonds in a gaseous molecule

23
Q

Standard enthalpy change of formation

A

The enthalpy change when one mole of a compound is made from its elements in their standard state under standard conditions (1 atm and 25 degrees)

24
Q

Standard enthalpy change of combustions

A

Enthalpy change when one mole of substance undergoes complete combustion under standard conditions

25
Standard enthalpy change for neutralisation
Enthalpy change on the formation of one mole of water from the neutralisation of acid with an alkali under standard conditions
26
Hesse's law
States that an enthalpy change for a reaction is independant of the route taken (providing the initial and final condition are the same)
27
Heterogenous catalyst
A catalyst that is in a different phase (physical state) to the reactants
28
Homogenous catalyst
Same phase as reactants
29
Dynamic equilibrium
A reversible reaction where the rate of the forward reaction is equal to the rate of the backward reaction
30
Structural isomers
Same molecular formule but different structural formula
31
Aliphatic
Straight chains only
32
Homologous series
Compounds with the same functional group and general formula but successive members differ by CH2
33
Functional group
An atom or group of atoms in a compound that determine the characteristic reactions of the molece
34
Radical
An atom of group of atoms with an unpaired electron
35
Homolytic fission
Each bonding atom receives one electron from the bonding pair forming two radicals
36
Isomer
Compounds with the same molecular formula but different chemical structures
37
Stereoisomers
Same structural formula but a different arrangement in space
38
Electrophile
An electron pair acceptor
39
Makownikoff's rule
The carbocation with the most alkyl groups on the C with the + sign will form as it will be the most stable
40
Nucleophile:
An electron pair donor
41
Volatility
Indicates how easily a liquid will change into a gas
42
Le Chatelier's principle
The position of equilibrium will shift so as to minimise the effect of any change in condition