Definitions & Decay Flashcards
Stable isotopes
Reference to light elements.
Light elements have a large percentage difference in the masses of their isotopes. Behave differently by various physical & chemical processes.
Examples of stable isotopes
H, C, N, O, S and Cl, Li, B, Si
How to measure isotopes in water
Waters are equilibriums with CO2 and fed into mass spec
Measuring isotopes in carbonates
Carbonate mineral is converted to CO2 gas
Reference standard for oxygen
Waters reference VSMOW
Waters depleted in 18O reference SLAP
Oxygen in carbonates reference VSMOW or VPDB
VSMOW
Vienna standard mean ocean water
SLAP
Standard light Antarctic precipitation
VPDB
Vienna pee dee belemnite
Reference standard for hydrogen
Rations are referred to VSMOW
Reference standard for Carbon
Referenced to VPDB
Reference of S
To CDT (canon diablo troilite)
Reference N, NO2 and He
Atmospheric nitrogen
Reference chlorine
SMOC (standard mean ocean chloride)
3 ways for thermodynamic fractionation
1) equilibrium physiochemical exchange
2) non- equilibrium reactions (kinetic controlled)
3) molecular diffusion
Molecules with a ______ isotope can diffuse out of a system more rapid than a molecule with a _____ isotope
Light
Heavy
Heavy isotopes react ______ when forming a bond and breaking a molecule that doesn’t want to be broken
Faster
Disequilibrium factor
The heavier isotope forms the stronger bonds and has a greater tendency to react rapidly & form a new compound.
If bonds are too strong equilibrium _____ occur
cannot
If the new compound is physically removed from the system ______ can occur
fractionation
Half-life
Time it takes for half of the atoms to decay into a new isotope
Beta Decay
Really common. Transformation of a neutron into a proton plus an electron.
Atomic number increases by 1, neutrons decrease by 1
Positron Decay
A proton changes into a neutron releasing a positively charged electron and energy.
Atomic number decreases and neutrons increase
Electron Capture
An electron is captured from the electron cloud. A proton is turned into a neutron because of electron absorption.
Atomic number decreases and neutrons increase
Alpha decay
Common mode of decay. Alpha particles consist of 2 protons and 2 neutrons.
Atomic number decreases by 2 neutrons decrease by 2 and mass number decreases by 4