Developing Fuels(DF) Flashcards

1
Q

What is an exothermic reaction?

A

A reaction that releases energy/heat to the surroundings, causing the temperature of the surroundings to increase

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2
Q

In an exothermic reaction does the products or reactants have more energy?

A

Reactants

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3
Q

What happens to the difference in energy between reactants and products in an exothermic reaction?

A

The difference is release to the surroundings

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4
Q

What is an endothermic reaction?

A

A reaction that takes in heat/energy from the surroundings, causing the temperature of the surroundings to decrease

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5
Q

In an endothermic reaction does the products or reactants have more energy?

A

Products

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6
Q

What is activation energy?

A

The miniumum amount of energy that particles must have to react

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7
Q

What is a catalyst?

A

A catalyst is something which increases the rate of reaction, by providing an alternative pathway for the reaction with a lower activation energy, without being used up

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8
Q

Why are catalysts not involved in the chemical equation for a reaction?

A

They are not used up during the reaction

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9
Q

What are the benefits of using a catalyst?

A

-Allows a reaction to happen at a lower temperature=saves energy
-Saves money

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10
Q

What is enthalpy ΔH ?

A

The measure of heat energy in a system

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11
Q

How can you calculate enthalpy change?

A

ΔH =H products- H reactants

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12
Q

What is enthalpy change measure in?

A

kJ mol-1

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13
Q

For an exothermic reaction will the enthalpy change be positive or negative?

A

Negative

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14
Q

For an endothermic reaction will the enthalpy change be positive or negative?

A

Positive

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15
Q

What is the equation that links energy released, mass, specific heat capacity and temperature change?

A

Q = mc∆T

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16
Q

Does breaking bonds release or take in energy?

A

Takes in energy

17
Q

Does making bonds release or take in energy?

A

Releases energy

18
Q

What happens as bond length decreases?

A

The bond becomes stronger

19
Q

Why might calculated bond energy value differ from the figure provided?

A

-Bond energies are average values from several compounds=not always precise
-Bond energies assume all molecules are in a gaseous state

20
Q

If the energy needed to break the bonds is greater than the energy released when the new bonds are made is the reaction endo or exothermic?

A

Endothermic

21
Q

If the energy needed to break the bonds is less than the energy released when new bonds are made the reaction is the reaction endo or exothermic?

A

Exothermic

22
Q

Describe how to calcuale the enthalpy change of solution?

A
  1. Place known volume of water into a polystyrene beaker
    2.Add known mass of the other compund to the water and stir
    3.Measure temperature of water before and after
23
Q

Can atoms rotate freely around a single or double bond?

A

Single bond, in a double bond there is restricted rotation

24
Q

What are stereoisomers?

A

Molecules with the same structural formula but the atoms have a different spacial arrangment

25
What are the two types of stereoisomers?
E and Z
26
What is Z isomerism?
When the two highest-priority substituents are on the same side of the double bond axis
27
What is E isomerism?
When the two highest-priority substituents are on opposite sides of the double bond axis
28
What is cis-trans isomerism?
Alkenes with exactly two substituents on the double bond - with one on each carbon
29
What is cis isomerism?
When the substituents are on the same side of the carbon double bond
30
What is trans isomerism?
When the substituents are on different sides of the carbon double bond
31
What direction do the arrows point for enthalpy changes and what is the equation?
* Combustion=inwards * H1=H2-H3 * Formation=outwards * H1=H3-H2 | Formation=natural state of elements
32
What is the standard enthalpy change of combustion?
The enthalpy change that occurs when mole of a substance is burnt completely in oxygen under standard conditons
33
What does aromatic,aliphatic and arene mean?
* Aromatic=contains a benzene ring * Aliphatic=does not contain a benze ring * Arene=hydrocarbon containing a benzene ring