disproportionate reactions Flashcards
(13 cards)
disproportion reaction
element Is both oxidised and receded in the same reaction
what elements will displace each other in a displacement reaction
A halogen will displace (oxidise) the halide from a solution if it is below it on the periodic table
How to test for halides
1- add dilute nitric acid,
2- Add silver nitrate ( ag No3) - it reacts with the halide ion present
3- precipitate is formed of silver halide
The colour of ppt and the solubility in diff ammonia solutions when testing for halides.
cl- forms white ppt and dissolves in dilute nitric acid
br- forms cream ppt and dissolves in conc nitric acid
I- forms cream ppt and is insoluble in conc nitric acid.
How to confirm the halide present
add ammonia solution - diff solubility for diff halides
Halogen disproportionate reactions with…
- cold dilute alkali solutions -oxidised and reduced.
what happens when u mix chlorine with sodium hydroxide
mix chlorine gas with cold dilute sodium hydroxide you make sodium chlorate solution (bleach)
- 2NAOH + CL2 -> NACLO + NACL + H20
benefits of sodium chlorate solution (bleach)
water treatments (kill bacteria) , bleach paper and textiles, cleaning
what happens when you mix chlorine and water
- when you mix chlorine and water it undergoes disproportionation reaction. (0 to -1, +1)
- mixture of HCL and HCLO (Chloric acid) produced
- chloric acid ionises to form chlorate ions
- chlorate ions kill bacteria
Benefits of adding chlorine to water
-kills disease causing microorganisms
- prevents reinfection
- prevents algae growth - bad smells, taste, removes discolouration
Risks of adding chlorine to water
-hazard of toxic chlorine gases - respiratory issues
- chemical bruns - cl(l)
- possible risk of cancer from formation of chlorinated hydrocarbons (eg; decomposition of plants in water)
alternatives to using chlorine as a method of killing microorganisms
- ozone (03) (good oxidising element - good at killing microorganisms)
- Uv -> damages DNA of micro-organisms, ineffective in cloudy water though.
what ppt formed (displacement reaction) of ammonium carbonate and barium nitrate
a white ppt of barium carbonate