disproportionate reactions Flashcards

(13 cards)

1
Q

disproportion reaction

A

element Is both oxidised and receded in the same reaction

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2
Q

what elements will displace each other in a displacement reaction

A

A halogen will displace (oxidise) the halide from a solution if it is below it on the periodic table

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3
Q

How to test for halides

A

1- add dilute nitric acid,
2- Add silver nitrate ( ag No3) - it reacts with the halide ion present
3- precipitate is formed of silver halide

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4
Q

The colour of ppt and the solubility in diff ammonia solutions when testing for halides.

A

cl- forms white ppt and dissolves in dilute nitric acid
br- forms cream ppt and dissolves in conc nitric acid
I- forms cream ppt and is insoluble in conc nitric acid.

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5
Q

How to confirm the halide present

A

add ammonia solution - diff solubility for diff halides

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6
Q

Halogen disproportionate reactions with…

A
  • cold dilute alkali solutions -oxidised and reduced.
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7
Q

what happens when u mix chlorine with sodium hydroxide

A

mix chlorine gas with cold dilute sodium hydroxide you make sodium chlorate solution (bleach)
- 2NAOH + CL2 -> NACLO + NACL + H20

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8
Q

benefits of sodium chlorate solution (bleach)

A

water treatments (kill bacteria) , bleach paper and textiles, cleaning

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9
Q

what happens when you mix chlorine and water

A
  • when you mix chlorine and water it undergoes disproportionation reaction. (0 to -1, +1)
  • mixture of HCL and HCLO (Chloric acid) produced
  • chloric acid ionises to form chlorate ions
  • chlorate ions kill bacteria
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10
Q

Benefits of adding chlorine to water

A

-kills disease causing microorganisms
- prevents reinfection
- prevents algae growth - bad smells, taste, removes discolouration

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11
Q

Risks of adding chlorine to water

A

-hazard of toxic chlorine gases - respiratory issues
- chemical bruns - cl(l)
- possible risk of cancer from formation of chlorinated hydrocarbons (eg; decomposition of plants in water)

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12
Q

alternatives to using chlorine as a method of killing microorganisms

A
  • ozone (03) (good oxidising element - good at killing microorganisms)
  • Uv -> damages DNA of micro-organisms, ineffective in cloudy water though.
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13
Q

what ppt formed (displacement reaction) of ammonium carbonate and barium nitrate

A

a white ppt of barium carbonate

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