Dr Fawzy GIC Flashcards
(151 cards)
What is the composition of GIC?
Ion-leachable glass
Water soluble polyacids
Water
What kind of reaction is the setting reaction of GIC?
An acid-base reaction
How does GIC adhere to the tooth?
Ionic bonding
Micromechanical bonding
What is the composition of RMGI?
Ion-leachable glass
Water soluble polyacids (may be methacrylate modified)
Methacrylate monomers
Water
Photoinitiators
What kind of reaction is the setting reaction for RMG1?
Free radical polymerization
Acid-base reaction
What kind of adhesion does RMG1 use to bond with tooth?
Ionic bonding
Micromechanical adhesion
What is the compomer composed of?
Ion-leachable glass
Glass and silica fillers
Dimethacrylate monomers
Polyacid-modified methacrylate monomers
Photoinitiators
Silane coupling agents
What does the compomer use for setting reaction?
Free radical polymerization
Acid-Base reaction (delayed)
What is the type of adhesion that occurs with the tooth in the compomer?
Micromechanical with adhesive
What is the resin-based composite composed of?
Glass and silica fillers
Dimethacrylate monomers
Photoinitiators
Silane coupling agents
What type of setting reaction does the resin-based composite reaction use?
Free radical polymerization
What type of adhesion does resin-based composite adhere to the tooth with?
Micromechanical with adhesive
What are the biological requirements of restorative materials?
They must be:
Non-toxic
Cariostatic
What are the physical requirements of restorative materials?
Should not erode or dissolve in saliva or fluid taken into the mouth
Good resistance to wear and fracture
Thermal properties similar to that of the tooth
Should adhere to tooth structure
Dimensional changes on setting should be low
Good polishability and retain a smooth finish
Radiopaque
Should have good and long term aesthetics
What are the types of tooth coloured restorative materials?
Cements such as silicate cements and glass ionomer cements.
Dental resins such as acrylic (unfilled) resins and composite (filled) resins
Dental ceramics
What kind of differences are seen between the types of direct tooth-coloured restorative materials?
A continuum exists between conventional glass ionomer and composite resins based on how much of the reaction is acid-base and how much is resin polymerization.
Conventional glass ionomer is more dependent on acid-base reaction and composite resins are more dependent on resin polymerization.
Continuum is as follows:
100% Acid-base reaction - Conventional Glass Ionomer -> Resin-modified Glass ionomer -> Compomer -> Composite resins - 100% Resin polymerization reaction
What are silicate cements used for?
For class 3 and 5 restorations
What are the limitations of using silicate cements?
Stains easily
Prevents secondary caries
Poor marginal adaptation leading to seepage and pulp death
What is the composition of silicate cement powder?
Silica
Alumina
Sodium or calcium phosphate
Sodium or calcium fluoride
Arsenic
What is the composition of silicate cement liquid?
42% phosphoric acid
10% Aluminum phosphate
8% Zinc phosphate
40% Water
How does setting of silicate cement take place?
Hydrogen ions from the phosphoric acid attack the glass (outer surface) and displace the aluminum ions. Other ions are also displaced together with the fluoride ions
pH rises and the metal phosphates and fluorides precipitate to form the matrix which is mainly hydrated aluminum phosphate.
Surface of the powder particle remains as a hydrated alumino silicate gel due to replacement of the metal ion by hydrated protons.
What is the final product of the setting of silicate cement?
Set cement is a composite material consisting of:
An inner core of unreacted positively charged particles.
A middle layer of siliceous gel bonded to the core by means of Si-O-Al bonds.
An outer layer of hydrated aluminum phosphate gel bonded to the siliceous gel by H-bonded molecules. (Water is essential for the formation of the cement, matrix forms 20 - 30% of the cement)
What are the pros and cons of using silicate cements?
Cons:
Shrinks on hardening (Greater shrinkage occurs when it is allowed to dry out causing discoloration around the margins)
Dissolves and disintegrates in the oral fluids (Decreases with time and is accelerated by citrus fruits)
Weakest of all tooth-coloured restoratives (exception of unfilled resin)
Tends to discolour with time.
Has high acidity and an initial pH of 2.8 which increases to 5.8 after 28 days.
Pros:
Has good thermal properties
Has an anti-cariogenic effect attributed to fluoride release from the cement
How does silicate cement carry out anti-cariogenic actions?
Fluoride reduces enamel acid solubility
Fluoride acts as an enzyme inhibitor to prevent carbohydrate metabolism by bacteria
Fluoride reduces the wettability of the enamel and thus makes plaque accumulation more difficult
Postulated that phosphoric acid present has initial inhibitory effect on bacterial growth for 24 to 48 hours