Electronic Structure & Atomic Behavior Flashcards

1
Q

As you move across a period, atomic radius _____

A

Decreases (Zeff increase which means more protons in the nucleus which cause a stronger pull causing it to decrease)

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2
Q

Second & higher ionization energy

A

Second ionization energy is the energy required to remove a second outermost electron from a ground state atom

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3
Q

Exceptions to electron configurations

A

Expected: [Ar] 4s23d4

Actual: [Ar] 4s13d5

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4
Q

Amplitude

A

Wave’s height from zero to the creest

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5
Q

Bright Line Spectrum

A

The characteric light emitted by energertically excited atoms of an element as an electron fall from a higher to lower energy state

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6
Q

When atoms abbsorb energy electrons move into _____ energy levels where electrons then lose energy by ________ light when they return to lower energy level

A

Higher Energy levels, Emitting light

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7
Q

Isoelectronic series

A

Ions have the same number of electrons

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8
Q

Ground State

A

Lowest possible energy level

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9
Q

How to you determine which atoms is larger than the other within an isoelectronic series?

A

The number of protons it has

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10
Q

Electronegativity

A

A measure of the ability of an atom in a molecule to attract electrons to itself

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11
Q

Atoms with high ionization energy forms _______

A

Anions

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12
Q

When ions are formed, valence electrons are _____ or _______ to establish stability & become ______ with a noble gas

A

Gained or lost; isoelectronic

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13
Q

Cations are _______ their regular atom

A

Smaller

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14
Q

The _______ the electron affinity for an electron, the more energy is released when an electron is added

A

Larger

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15
Q

Wave length

A

Distance between the crest

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16
Q

Ferromagnetism

A

Occurs when the spins of unpaired electrons in a cluster of atoms in a solid align themselves in the same direction

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17
Q

The lower the energy level the more ______ the atom

A

Stable

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18
Q

Diamagnetic

A

Occur when electrons are paired

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19
Q

Photoelectric effect

A

Occurs when light strikes the surface of a metal & electrons are released

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20
Q

Excited State

A

Higher energy level

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21
Q

Atomic Emission Spectrum

A

The frequencies of light emitted by an element into discrete lines

22
Q

Pauli Exclusion Principle

A

States no two electrons can have the same set of quantum number (oribitals can only hold two electrons with opposite spins)

23
Q

Octect Rule

A

States that atoms are most stable when they have a full shell of electrons in the outermost ring

24
Q

Lowest first ionization energy is usually within what group?

25
As you move across a period, electron affinity \_\_\_\_\_\_\_
Increases
26
Destructive
When two waves are out of phase & cancel out one another out (Produce darkness)
27
As you move across a period, first ionization energy \_\_\_\_\_\_\_\_\_
Increases
28
Photons are only ejected when the ________ of the light exceeds a certain thresold value for each particular metal
Frequency
29
Anions are ______ their regualr atom
Larger
30
Uncertaainty Principle
States that cant know the both the location & momentum of an electron at any given time
31
As you move down a group, atomic radius \_\_\_\_\_
Increase
32
Hunds Rule
The lowest energy configuration for an atom is the one having the maximum number of unpaired electrons allowed
33
Electronegativity _____ as you go down a group
Decreases
34
Frequency
Is the number of waves cycles to pass a given point per unit of time (SI unit Hz)
35
Sheilding
Inner electrons at lower energy levels essentially blocks the proton's force of atrraction toward the nucleus
36
Why does ionization energy increase as you move across the period?
It increases because as you move across the period the size decreasesand electrons become closer to the nucleus)
37
Paramagnetism
Occurs when electrons are unpaired
38
Wave length & frequency are _______ to one another
Inversely Proportional
39
Rules for stability
1. Full energy level (Most stable) 2. Full subshell 3. 1/2 filled subshell 4. Full oribital 5. 1/2 filled oribital (least oribital)
40
Electron Affinity
The energy given off when a neutral atom in the gas phase gains an extra electron to form a negatively charged ion
41
The electron affinity becomes more _______ as you move across a period because the Zeff ________ therefore increasing the attraction for an electron
More negative, Increases
42
Constructive
When two waves are in phase & combine to make a larger wave increase that waves amplitude (Produce light)
43
Highest 1st ionization is usually within what group?
Group 8A
44
Energy & frequency are _______ to one another
Directly Proportional
45
Aufbau Principle
Electrons fill lowest energy oribitals first
46
As you down a group, electron affinity \_\_\_\_\_\_\_
Decreases
47
Energy is ________ proprtional to the frequency of a wave
Dirtecly proportional
48
First Ionization energy
The energy required to remove the outermost electron from an atom in the the ground state
49
Electronegativity ______ across a period
Increases
50
Atoms with low ionization energy forms \_\_\_\_\_\_
Cations
51
As you move down a group, first ionization energy \_\_\_\_\_\_\_\_\_
Decrease
52
Diffraction
The bending of waves through a narrow, small, opening