ENTHALPY Flashcards

(45 cards)

1
Q

is the reaction with oxygen to produce small molecules such as CO2 and H2O

A

Combustion

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2
Q

liquid to solid

A

freezing

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3
Q

gas to liquid

A

condensation

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4
Q

gas to solid

A

deposition

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5
Q

Exothermic Processes

A

Combustion
Phase Changes: Freezing, Condensation, Deposition
Dissolution
Bond Formation
Electron Gain

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6
Q

two unstable atoms may form a stable molecule

A

Bond Formation

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7
Q

some ionic compounds that dissociate into ions in water release energy

A

Dissolution

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8
Q

electron affinity is the energy released when a gaseous atom accepts an electron

A

Electron Gain

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9
Q

these processes are accompanied by lowering of the temperature (cooling) of the surroundings

A

Endothermic Process

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10
Q

this can sometimes be endothermic

A

Dissolution

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11
Q

Endothermic Process

A
  • Phase Changes: Fusion, Vaporization, Sublimation
  • Bond Dissociation
  • Ionization
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12
Q

solid to liquid

A

fusion

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13
Q

liquid to gas

A

vaporization

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14
Q

solid to gas

A

sublimation

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15
Q

is the energy needed to break a bond joining two atoms

A

bind dissociation energy

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16
Q

is the energy needed to remove an electron from a gaseous atom

A

Ionization Energy

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17
Q

are process that release heat to surroundings

A

Exothermic processes

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18
Q

are processes that absorb heat from the surroundings

A

Endothermic Processes

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19
Q

is the sum of the internal energy (E) and the product of work at constant PRESSURE

20
Q

is the expansion and compression of the system, therefore it is brought upon the change in PRESSURE and VOLUME

21
Q

at constant pressure, enthalpy of a process is equal to the ________

22
Q

is the difference between the enthalpies of product and enthalpies of reactants

A

enthalpy of reaction

23
Q

enthalpy change of solid to liquid

A

enthalpy of reaction
enthalpy of fusion

24
Q

enthalpy change of phase 1 to phase 2

A

enthalpy of translation

25
enthalpy change of liquid to gas
enthalpy of vaporization
26
enthalpy change of solid to gas
enthalpy of sublimation
27
enthalpy change of solute to solution
enthalpy of solution
28
enthalpy change of elements to compound
enthalpy of formation
29
enthalpy change of compound
enthalpy of combustion
30
delta H < 0 (negative value)
exothermic
31
delta H > 0 (positive value)
endothermic
32
is an extensive property (depends on the amount of substance involved in a process)
Enthalpy Change
33
is the enthalpy change accompanying a process undergone by 1 mole of a substance
Molar Enthalpy Change
34
is the physical state of a pure substance in its most stable form at 1 atm and 25 degrees celsius
thermodynamic standard state
35
is the enthalpy change involved in the formation of 1 mole of a substance from elements in their standard states
standard enthalpy of formation of standard heat of formation
36
is the enthalpy change involved in a chemical reaction at standard conditions (1 atm and 25 degrees celsius)
standard enthalpy of reaction of standard heat of reaction
37
is it equal to the sum of the standard heats of formation of products less the sum of the standard heats of formation of reactants
standard enthalpy of reaction of standard heat of reaction
38
is the sum of internal energy and the product of pressure and volume
enthalpy of a system
39
is equal to heat at constant pressure. It gives us an idea whether the process is exothermic or endothermic
enthalpy of a process
40
is a chemical equation that indicates the energy, particularly the heat of enthalpy change, that accompanies the reaction
thermochemical equation
41
for an exothermic reaction, the sign of the standard heat of reaction is _________
negative
42
for an endothermic reaction, the sign of the standard heat of reaction is ________
positive
43
is the sum of the enthalpy changes of all steps leading to this reaction
enthalpy of a reaction
44
change in enthalpy of a chemical reaction depends upon the initial and final state of a chemical reaction irrespective of the number of steps involved in a chemical reaction
Hess's Law
45
this law states that the enthalpy of a reaction is the sum of the enthalpy changes of the steps leading to this reaction
Hess Law