THERMODYNAMICS Flashcards

(60 cards)

1
Q

is the transfer of energy as disorderly motion as a result of a temperature difference between the system and the surrounding

A

Heat

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2
Q

q (+) and w (+), internal energy?

A

increases

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3
Q

Value does not depend on the amount of the material present. (e.g: density, temperature)

A

Intensive Property

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4
Q

________________ of a substance is the amount of heat required to raise the temperature of a given amount of the substance by one degree Celsius

A

Heat capacity (C)

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5
Q

Deals with the study of energy and its transformation.

A

Thermodynamics

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6
Q

The greater the __________, the greater the heat required to produce a given increase in temperature

A

Heat Capacity

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7
Q

Heat evolved by the system

A

Exothermic (-q)

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8
Q

The change in Energy is the sum of the

A

Heat exchanged and work done

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9
Q

means it does not allow matter to pass through it

A

impermeable

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10
Q

is the energy utilized to cause an object to move against an opposing force

A

Work

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11
Q

Heat added to the system

A

Endothermic (+q)

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12
Q

Types of System

A

Open System
Closed System
Isolated System

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13
Q

Work done on the system

A

+w

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14
Q

“the capacity to do work or even transfer heat to cause a change in temperature”

A

Energy

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15
Q

It depends on mass, temperature and state of the system

A

Internal Energy

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16
Q

It can be adiabatic or nonadiabatic (diathermal)

A

Boundary/Wall

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17
Q

It can be rigid (immovable) or non-rigid (movable)

A

Boundary/Wall

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18
Q

is the total change in internal energy of a system

A

ΔEsys

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19
Q

states that in the process, the change in energy of a system is equal to the heat absorbed (q) by the system and the work (w) done on it

A

The First Law of Thermodynamics

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20
Q

characterized by a free exchange of matter and energy

A

Open System

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21
Q

Heat (q) and work (w) are _________ when they enter the system

A

Positive

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22
Q

The law implies that the net energy flow to or from any system comes in the form of either

A

Work or Heat

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23
Q

depends on the path by which a system in one state is changed into another state. The value changes depends how the system came to be

A

Path Function

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24
Q

“energy cannot be created nor destroyed. It can be transformed into another form, but the total amount of energy remains the same”

A

First Law of Thermodynamics: Law of Conservation Energy

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25
there is still a free exchange of energy but in terms of matter, the exchange with the surroundings is not possible due to an impermeable wall which not allows the flow of mass from system to surroundings and vice-versa
Closed System
26
the exchange of both matter and energy to the surrounding is not possible because of having a wall that is impermeable and adiabatic
Isolated System
27
include everything else except the system in the universe
Surrounding
28
value of a given property depends only on the state of the system. It is independent of the manner the state is attained
State Function
29
Work done by the system
-w
30
is the amount of heat required to raise its temperature by 1 K (or 1 °C) of 1 g of a substance
Specific heat capacity (c)
31
separate the system and the surroundings
Boundary/Wall
32
“thermes”
heat
33
Heat added to the system
Endothermic (+q)
34
the change in heat in any physical or chemical processes are measured with an instrument called
Calorimetr
35
both matter and energy can flow from the system to the surroundings or from surroundings to system
Open System
36
Heat added to the system
Endothermic (+q)
37
q (+) and w (-) q (-) and w (+) internal energy?
The sign of ΔE depends on the magnitude of q and w
38
A system can exchange energy with its surrounding through heat, work, or both.
The First Law of Thermodynamics
39
allowing heat to pass through
non-adiabatic
40
It can be permeable or impermeable
Boundary/Wall
41
nom-rigid
movable
42
Heat (q) and work (w) are _________ when they leave the system
Negative
43
From the Greek word : “thermes” - heat , “dynamo” - power
Thermodynamics
44
Thermodynamics Properties may be
Extensive Property Intensive Property
45
It determines if the system expands or compressed
Work
46
“dynamo”
power
47
Ex.: Work and Heat
Path Function
48
Thermodynamics Properties can also be
State Function Path Function
49
is the process of measuring the amount of heat that is either released or absorbed during a physical or chemical reaction
Calorimetry
50
It is the sum of Potential Energy and Kinetic Energy within the system.
Internal Energy
51
It is the transfer of energy as orderly motion
Work
52
Ex.: volume, pressure, internal energy, entropy
State Function
53
Thermodynamics only deals the
Change in Internal Energy
54
specific part of the universe that is under our interest
System
55
q (-) and w (-), internal energy?
decreases
56
heat cannot be pass through
adiabatic
57
It is a state function
Internal Energy
58
rigid
immovable
59
Value depends on the amount of material present. (e.g: mass, volume, internal energy)
Extensive Property
60
Enable us to understand the energetics and directions of reactions.
Thermodynamics