enthalpy + entropy Flashcards
(13 cards)
what is the free energy equation
ΔG = ΔH - TΔS
entropy equation
ΔS= ΔSproducts - ΔS reactants
define enthalpy of solution
enthalpy change when one mol of a compound is dissolved
enthalpy change of hydration
when 1 mol of gaseous ions produces 1 mol of aqueous ions
define lattice enthalpy
enthalpy change when 1 mol of an ionic lattice is formed from its gaseous ions
what are the two factors that effect lattice enthalpy?
charge and radius
what happens to lattice enthalpy as ionic radius increases?
becomes less extothemic
what happens to lattice enthalpy as charge increases?
becomes more exothermic
what are the two factors that effect enthalpy of hydration?
charge and radius
what does a negative ΔS value mean?
products less disordered than reactants
what does a positive ΔS value mean?
products more disordered than reactants
what does a positive ΔG mean?
reation is not feasible
what does a negative ΔG mean?
reaction is feasible