Enthaply and Entropy Flashcards

1
Q

what does the lattice enthaply mean?

A

the enthalpy change that accompanies the formatuions of one mole of an ionic compound from its gaseous ions under standard conditions

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2
Q

latice enthaply down a group

A

ionic rradius increases

attraction between ions decreases

lattice energy less negative

melting point decreases

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3
Q

lattice enthaply across a period

A

ionic charge increases

attraction between opns increases

lattice enthaply more neagive

melting point increases

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4
Q

can we measure lattice enthaply directly?

A

No, we use an enthaply diagram to work it out

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5
Q

what is the standard enthaply change of atomisation?

A

the enthaply change when a mole of gaseous atoms is formed from elemetns in their standard states (298k, 1` atm)

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6
Q

what is the 1st ionisation energy

A

the amount of energy required to remove one electron from every atom in one mole of gaseous atoms to form a mole of gaseous 1+ ions

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7
Q

what is the 2nd ionisation energy?

A

the amount of energy required to remove one electron from every ion in one mole of gaseous 1+ ions to form a mole of gaseous 2+ ions

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8
Q

what is the standard enthaply change of formation?

A

the enthaply chagne when a mole of a compound is formed from its elements in thier standard states, under standard condition (1atm, 298k)

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9
Q

what is first electron affinity

A

the enthalpy change that takes place when one electrons is added to each atom is one mole of gaseous atoms to form one mole of gaseous 1- ions.

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10
Q

what is the second electron affintiy?

A

the enthalpy change that takes place when one electrons is added to each ion is one mole of gaseous 1- ions to form one mole of gaseous 2- ions.

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11
Q

what to remember when there is a second electron affinity?

A

the second electron affintiy must contain an electron

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12
Q

waht does lattice enthaply equal to?

A

enthaply change of formation - everythign elese

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13
Q

what is the standard enthaply change of solution?

A

the enthaply change when a mole of an ionic solid compound is completely dissolved in water under standard conditions (298k, 1 atm)

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14
Q

what type of reaction is more soluble?

A

exothermic means more soluble

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15
Q

what is the standard enthaply change of hydration?

A

The exotrhermic enthaplky change when a mole of isolated gaseous ions is dissolved in water to from a mole of aquesous ions under standard condition (298k, 1 atm)

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16
Q

what does a born haber cycle with solution and hydration look like?

A
17
Q

what is entropy?

A

a measure of the dispersal of ernergy in a system which is greater, the more disordered a system

18
Q

States from least to most entropy

A

solid

liquid

solutions

gases

19
Q

what has a higher entropy, 2 or 4 moles of gas?

A

4 moles of gas

20
Q

how to calculate the entropy?

A

entropy of products - entropy of reactatns

21
Q

how to calculate entropy?

A

entropy of products - entropy of reactatns

22
Q

what is the gibbs free energy equation

A
23
Q

when is a reaction spontaneous/feasable?

A

when ΔGis -ve

24
Q

what does a normal born hber cycle look like?

A
25
Q

what does successive electron affinities look like?

A
26
Q

what are the lattice enthaply routes?

A