equilibrium 1&2 Flashcards

(22 cards)

1
Q

what does dynamic equilibrium mean

A

the rate of the forward reaction is the same as the rate of the backward reaction in a closed system, and the concentrations of the reactants and products are constant

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2
Q

what does it mena if equlinrium lies to the left/right in relation to prducts and reactants

A

left - when there is more reactants than products in the equilibrium mixture
right - when there is more products than reactants in the equilibrium mixture

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3
Q

factors affecting position of equilbrium

A
  • concentration of a component
  • pressure of a system
  • temperature
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4
Q

what does homogenous system mean

A

homo XD
- all reactants nad products are in the same phase

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5
Q

what does heterogenous system mean

A

at least 2 different phases are present

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5
Q

what does a phase mean

A
  • like state but allows liquids that are immersible to be different phases
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5
Q

what doe s alarge Kc value mean

A

the qeuilibrium lies to the right

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5
Q

Kc=

A
  • [prodcuts]/[reactants]
  • constant, same value at same temperature, unaffected by pressure
    eg. aA + bB —> cC + dD
    so Kc = [C]^c x [D]^d/[A]^a x [B]^b
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6
Q

what is Q
ask a teacher perchance xx

A

mathematical realtionship between concentrations of components in a reaction
q=kc

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7
Q

what does a small Kc means <1

A

equilibrium lies to the left

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8
Q

how to calculate Kc

A

i - initial moles
c - change in moles
e - equilibrium moles
c - concnetration at equlibrium (eq moles/volume)
substitute the concnetrations into the [products]/[reactants] equation

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9
Q

what is le chatelier’s prinicple

A

if a change is made to a system in dynamic equilibrium, the position of the equilibrium moves to counteract this change

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10
Q

how does changing temp affect the equilbrium and affect on Kc

A
  • if we increase temperature the equlibrium will shift to the endothermic direction
  • if the backwards reaction was endothermic, the denominator of Kc increases therefore Kc decreases
  • if the forwards reaction was enfothermic, the numerator of Kc would increase therefore Kc increases
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11
Q

how does changing pressure affect the equilbrium

A

An increase in pressure will cause the equilibrium to move towards the side with the fewest molecules.
A decrease in pressure will cause the equilibrium to move towards the side with the most molecules.

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12
Q

how does changing concentration affect the equilbrium and Kc

A
  • equilibrium will move towards the products in order to use up the extra reactant added
  • rate of the reaction temporarily increases and the system is no longer in equilibrium
  • Kc doesn’t change
  • if you incrrease concnetration of product number of Q increase so equlibrium shifts left to increase denominator and restore Q=Kc
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13
Q

Kp =

A

(p Products)/(p Reactants)

14
Q

partial pressure =

A

mole fraction x total pressure

15
Q

what is mole fraction

A

moles of individual gas/moles of all gas

16
Q

how does temperature affect Kp

A
  • favours endothermic side
  • denominator of Kp Increase thereofre Kp decreases
17
Q

how does change in partial pressure of one gas affect Kp

A

-ie. change in conc of one gas
- Kp doesn’t change
eg one reactnat increases:
- denominator of Q increases
- equilibrium shifts rigth tot restor Q=Kc

17
Q

how does change in total pressure affect Kp

A

equlibrum shifts ot side with fewest moles

18
Q

lowkey is there anythign else for Kp xx

A

tell me !! (wonder girls refrence what >.<)