Equilibrium II Flashcards
(9 cards)
What is Kp calculated in terms of
partial pressure
What is partial pressure
the pressure than an individual gas exerts on the container it is in
What is the equation for partial pressure
mole fraction x total pressure
What is the equation for mole fraction
moles of an individual gas / total moles of all gas
Give three conditions that affect Kp
1) temperature
2) partial pressure of one gas
3) total pressure of system
What effect does temperature have on the value of Kc
increase in temperature
equilibrium shifts left/right in the endothermic direction
Kp numerator / denominator increases
so Kp increases / decreases
What effect does the partial pressure of a specific gas have on the value of Kc
increase in the concentration of [X]
Kp remains constant
denominator / numberator of Q increases, so Q increases / decreases
so equilibrium shifts left / right to restore Q to equal Kc
How does a change in the total pressure in a system effect the value of Kc
increasing pressure will shift equilibrium right / left to the side with fewer moles
Kp remains constant
Describe how to calculate how changing the total pressure of a system effects the value of Kc
1) give each component of the Kc equation a letter
2) replace every letter in Q with the multiplication factor and apply powers from original equation
3) rearrange and find whether numerator / denominator increases
- if numerator increases, equilibrium shifts left to restore Q = Kc
- if denominator increases, equilibrium shifts right to restore Q = Kc