Equilibrium II Flashcards

(9 cards)

1
Q

What is Kp calculated in terms of

A

partial pressure

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2
Q

What is partial pressure

A

the pressure than an individual gas exerts on the container it is in

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3
Q

What is the equation for partial pressure

A

mole fraction x total pressure

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4
Q

What is the equation for mole fraction

A

moles of an individual gas / total moles of all gas

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5
Q

Give three conditions that affect Kp

A

1) temperature
2) partial pressure of one gas
3) total pressure of system

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6
Q

What effect does temperature have on the value of Kc

A

increase in temperature
equilibrium shifts left/right in the endothermic direction
Kp numerator / denominator increases
so Kp increases / decreases

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7
Q

What effect does the partial pressure of a specific gas have on the value of Kc

A

increase in the concentration of [X]
Kp remains constant
denominator / numberator of Q increases, so Q increases / decreases
so equilibrium shifts left / right to restore Q to equal Kc

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8
Q

How does a change in the total pressure in a system effect the value of Kc

A

increasing pressure will shift equilibrium right / left to the side with fewer moles
Kp remains constant

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9
Q

Describe how to calculate how changing the total pressure of a system effects the value of Kc

A

1) give each component of the Kc equation a letter
2) replace every letter in Q with the multiplication factor and apply powers from original equation
3) rearrange and find whether numerator / denominator increases

  • if numerator increases, equilibrium shifts left to restore Q = Kc
  • if denominator increases, equilibrium shifts right to restore Q = Kc
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