Exam 3 Flashcards

(53 cards)

1
Q

the ability to do work

A

Energy

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2
Q

Stored energy

A

Potential energy

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3
Q

Energy of motion

A

Kinetic energy

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4
Q

The transfer of Kinetic energy

A

Heat

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5
Q

The transfer of energy from one form to another

A

Work

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6
Q

Delta E= q + w
what does each of these stand for?

A

Delta E: Change in energy
q: heat energy
w: work

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7
Q

What type of temperature change is it when energy is on the reactant side of the equation?

A

Exothermic reaction

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8
Q

What type of temperature change is it when energy is on the product side of the equation?

A

Endothermic reaction

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9
Q

The part of the universe being studied

A

System

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10
Q

The rest of the universe

A

Surroundings

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11
Q

Energy cannot be created or destroyed

A

Law of conservation of energy

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12
Q

The total kinetic energy transferred from one substance or object to another

A

Heat

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13
Q

The average kinetic energy of the particles in a substance

A

Temperature

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14
Q

The amount of heat required to raise the temperature of the 1 gram of material by 1 degree celsius

A

Specific heat (s)

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15
Q

The amount of heat required to raise an object by 1 degree celsius

A

heat capacity (c)

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16
Q

Measure the flow of heat

A

Calorimetry experiments

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17
Q

Sm= - (Mw)(Sw)(delta Tw)/ (Mm)(delta Tm)

A

coffee cup calorimetry
m=mass
s=specific heat
delta T= change in temperature

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18
Q

Measures energy content (heats of reaction) in food and fuels

A

Bomb calorimetry

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19
Q

Equation used for bomb calorimetry

A

q=(C) (delta T)

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20
Q

Reaction energy is a…

A

Extensive property

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21
Q

Is the energy released in a combustion reaction

A

Fuel value

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22
Q

The amount of heat energy absorbed or released in a chemical reaction at constant pressure

A

Reaction enthalpy (delta H rxn)

23
Q

Delta H rxn=

A

-1,368 KJ
- means exothermic
+ means endothermic

24
Q

What are the two exceptions to the octet rule

25
How to draw a Lweis Dot Structure
1. Add up all the valence electrons 2. Frame the structure 3. Fill octets on outer atoms first 4. Fill the octet on the central atom
26
How to calculate the formal charge on atoms
formal charge= valence electrons in the neutral atom- number of covalent bonds- number of unshared atoms
27
-A set of structures that show how electrons are distributed -Used when a single Lewis structure is insufficient
Resonance structures
28
Arrangement of electrons around the central atom
Electronic geometry
29
Shape caused by the arrangement of atoms
Molecular geometry
30
Atoms do not share the electrons evenly
Polar covalent bond
31
How strongly atoms pull bonded electrons
Electronegativity
32
Polar covalent scale
less than 0.5- Covalent 0.5-2.0- Polar Covalent More than 2.0- Ionic
33
An overall polarity in a molecule
Molecular dipole
34
- particles are close together and held in a fixed place - Definite shape and volume
Solid
35
-Particles are closer together but move freely past each other - Definite volume; adopts the shape of the container
Liquid
36
-Particles are far apart and have very little interaction - Adopts shape and volume of container
Gas
37
A transition from one state of matter to another
Phase change
38
-Form lattices of tightly packed atoms -Electrons move easily between atoms -Shapes of metals are easily altered
Metallic substances
39
Forces within molecules are
Covalent bonds
40
Forces between molecules
intermolecular forces
41
Hydrogen bonding description and strength
--Molecules with H-F, H-O, or H-N bonds -Strongest type of intermolecular bond
42
Dipole-dipole forces description and strength
-Molecules with net dipole - in-between strength
43
London dispersion forces description and strength
-All covalent molecules -Weakest
44
The pressure and volume of a gas are inversely related
Boyle's Law
45
At constant pressure, the volume of a gas is directly proportional to its temperature
Charle's Law
46
How to convert Celsius to Kelvin
C + 273
47
The pressure caused by one gas in a mixture
Partial pressure
48
If temperature and pressure are constant, the volume of a gas is proportional to the number of moles of gas present
Avogadro's Law
49
The spread of particles through random motion
Diffusion
50
The process of a gas escaping from a container
Effusion
51
Lighter particles escape...
Faster
52
Heavier particles escape...
slower
53