Exam 4 ch 15 Flashcards
(11 cards)
eqillibrium expression
Homogenous: All same state, only aq invluded
Heterogeneous: different states, solids and liquids not included
Delta G and K
^G = -RTlnK
R = 8.314 J/molK
K forward and reverse
Forward: pro/rea = number
reverse = rea/pro = 1/number INVERSE
Large vs small K
Large: Product favored, spontaneous
Small: reactant favored, non spontaneous
Multiply reaction
Raise K to that number
Add reactions
Multiply Ks
Reaction quotient (Q)
-Like equillibrium constant but current concentrations
Q > K
Rxn proceeds towards reactants
Need more reactants
Q < K
Rxn proceeds towards products
Need more product
Q = K
Rxn at equillibrium
LaChatliers principle
-If a system is at equilibrium, the system will shift in a direction that reduces stress