EXERCISE 1 - 2 Flashcards

1
Q
  • almost all processes containing ____ have a need for pH measurement
A

WATER

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2
Q

compares the acidity or alkalinity of a solution at a given temperature

A

pH

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3
Q

neutral pH

A

pH 7

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4
Q

pH can only be measured if it is in ____ form

A

AQUEOUS

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5
Q

pH measures the dami ng

A

H+

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6
Q

neutral solution activity

A

H & OH are equal

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7
Q

acidic

A

ph < 7

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8
Q

acidic soln activity

A

H activity ↑ ; pH value ↓

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9
Q

basic

A

pH > 7

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10
Q

basic soln activity

A

OH activity ↑ ; pH value ↑

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11
Q

H activity and pH is

A

inversely proportional

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12
Q

the acidity and basicity of a substance can be measured in terms of

A

MOLAR CONCENTRATION

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13
Q

to provide ease in expressing these values, the concentration and OH- ions are denoted as

A

pH and pOH

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14
Q

the pH of a solution may be measured using

A

pH paper

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15
Q

measured the pH of the solution by changing its color depending on the concentration of H and OH ions

A

pH paper

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16
Q

pH paper is treated with an indicator known as

A

FLAVIN

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17
Q

flavin is an ____ commonly found in red cabbages

A

ANTHOCYANIN

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18
Q

flavin usually turns:

solution is acidic

A

RED

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19
Q

flavin usually turns:

solution is neutral

A

GREEN

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20
Q

flavin usually turns:

solution is basic

A

PURPLE

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21
Q
A
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22
Q
  • more accurate method than pH paper
  • contains a probe that passes the electrical signals to the meter itself which interprets the electrical signals and display the results on its screen
23
Q

two electrodes of ph meter

A

sensor
reference

24
Q

contains a pH 7 buffer

A

sensor electrode

25
usually contains **saturated KCl solution**
reference electrode
26
made up of **porous glass**; have both a **silver wire** covered with **silver chloride** or **calomel**
PROBE
27
pH meter probe has a silver wire that is covered with
silver chloride or calomel
28
* H ions are **spontaneously generated** in **pure water** by the **dissociation (ionization)** of a small percentage of water molecules * dissociation makes **equal numbers** of H and OH ions * while the OH ions can float around in solution as themselves, the H ions are transferred directly to a neighboring water molecule to form **hydronium ions**
AUTOIONIZATION OF WATER
29
# AUTOIONIZATION OF WATER H+ spontaneously ____ to **form** H+ and OH- **equally**
DISSOCIATES
30
the ____ of H+ causes it to **bind** to another H2O molecule, thus **forming a hydronium ion**
REACTIVITY
31
# AUTOIONIZATION OF WATER The amount of **dissociative H+** is ____ to the amount of **H3O+ formed**.
EQUAL
32
* **Acids** are species that **increase [H+]** * **Bases** are species that **increase [OH-]** * **Limited** in describing acidity and basicity to **dissociation** in **aqueous solution**
ARRHENIUS
33
# ARRHENIOUS Many substances **behave** as an **acid** or **base** in ____ phase where **no solvent** is **present**
GASEOUS PHASE
34
● **Acids** are proton **donors** - Must have a **H+** that can **dissociate** ● **Bases** are proton **acceptors** - Must have **at least one pair** of electrons to form a bond with a proton
BRONSTED-LOWRY
35
# BRONSTED react **almost completely** with **water**
STRONGER ACIDS | inorganic acids
36
react only **slightly** with **water**
WEAK ACIDS | acetic acid
37
**Acid strengths** are given using what values
pKa
38
acid **dissociation** constant
Ka
39
gives the **exact strength** of acid in water
Ka acid dissociation constant
40
There is an ____ relationship between **Ka** and **pKa**
INVERSE
41
* **Acids** **accept** a pair of non-binding **electrons** * **Bases** **donate** a pair of non-binding **electrons** * Suggest that **sharing electrons** between acids and bases causes **no change** in the **oxidation** numbers of any atoms.
LEWIS
42
Provided a way of **simplifying** the expression of [H+]
SORENSEN
43
pH means
pruissance d’ hydrogen
44
pruissance d’ hydrogen means
POWER OF HYDROGEN
45
how to compute for pH & pOH
-log [H+] -log {OH-]
46
how to compute for **[H+] [OH-]**
10‾pH 10‾pOH
47
formula for **pKw**
pKa + pKb = 14 pH + pOH = 14
48
* **Resist** change in pH * Most organisms, including humans, need to maintain pH within a **fairly narrow range** to survive * Consists of an **acid-base** pair, with the acid and base **differing** by the **presence** or **absence** of a **proton** (conjugate acid-base pair)
BUFFERS
49
# BUFFERS human blood involves what **acid**
CARBONIC ACID **H₂CO₃**
50
# BUFFER **conjugate base** of the human blood
BICARBONATE ION **HCO₃‾**
51
Used to calculate the pH of a **buffer** system
HENDERSON-HASSELBALCH
52
formula for **buffer**, weak **acids**
pH = pKa + log (salt/acid)
53
formula for **buffer**, weak **bases**
pH = pKw - pKb + log (base/salt)