Factors that Affect Reaction Rates Flashcards

1
Q

Temperature General Description

A

As temperature increases, reaction rate increases

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2
Q

Concentration of Reactants General Description

A

As concentration of reactants increases, reaction rate increases

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3
Q

Surface Area General Description

A

As surface area increases, reaction rate increases

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4
Q

Catalyst General Description

A

Presence of a catalyst increases reaction rate

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5
Q

Homogeneous catalyst

A
  • Same physical state as the reactants
  • Usually a gas or liquid
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6
Q

Heterogeneous catalyst

A
  • Different physical state from the reactants
  • Usually a solid
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7
Q

The Nature of the Reactants General Description

A

Chemical compounds vary considerably in their chemical reactions

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8
Q

Temperature - point A

A

As temp increases, more entities in the sample will have sufficient Ea to break bonds of reactants and form an activated complex

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9
Q

Temperature - point B

A

As temp increases, the rate of reaction increases therefore there will be an increase in the # of successful collisions between reactants

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10
Q

Maxwell-Boltzman Distribution

A

Relationship between Ea and KE

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11
Q

Concentration=

A

moles/volume

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12
Q

Concentration Point A

A

More particles in a particular space means more chances of colliding

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13
Q

Concentration Point B

A

Increasing pressure of a gas has the same effect as increasing concentration

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14
Q

Surface Area Point A

A

only atoms, ions or molecules at the surface of a solid can collide with other entities

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15
Q

Surface Area Point B

A

As surface area increases the probability of effective collisions increases aswell

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16
Q

What do catalysts not affect?

A
  • # of collisions
  • Kinetic energy
17
Q

What do catalysts do?

A
  • Provide an alternative pathway for the reaction that has a lower Ea
  • Increase reaction rate but do not get used up in reaction
18
Q

What does a positive catalyst do?

A

Lowers Ea

19
Q

What does a negative catalyst (inhibitor) do?

A

Increases Ea

20
Q

Why do gases react faster than liquids and solids?

A

Because they take less energy to overcome IMF’s

21
Q

What state reacts the fastest?

A
  • Aqueous ions
  • In aqueous solution, the ions of each compound are dissociated
22
Q

Bond Type

A

Less energy is required to break single bonds than double or triple bonds

23
Q

Bond Strength

A

Weaker bonds are broken at a faster rate

24
Q

Bond Number

A

Fewer bonds proceed faster

25
Q

What is another factor that affects Ea

A

Bond type, strength and number

26
Q

Size and shape of the molecule or ion

A
  • Complicated structures are less reactive
  • More bonds must be broken and they are less likely to collide in the correct orientation