Thermochemistry - Nature of Energy Flashcards

1
Q

What is thermochemistry?

A

The study of energy changes during physical or chemical changes in matter

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2
Q

What do all thermodynamics depend on?

A

The law of conservation of energy

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3
Q

The law of conservation of energy states…

A

Energy cannot be created nor destroyed

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4
Q

Potential Energy (PE)

A
  • Energy due to the position or composition of an object
  • Stored Energy
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5
Q

Examples of Potential Energy

A
  • Gravitational PE
  • Elastic PE
  • Chemical PE
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6
Q

Kinetic Energy (KE)

A
  • Energy of motion
  • Depends on mass of object and its velocity
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7
Q

Calculation of thermal energy

A

Thermal Energy=PE + KE

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8
Q

Changes that occur in matter may be classified into….

A

Physical, chemical or nuclear changes

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9
Q

Physical Change

A
  • Change in form or state of a substance
  • No chemical bonds are broken
  • Least energy
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10
Q

Example of physical change

A

Hydrogen boils at -252℃

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11
Q

Chemical Change

A
  • Change in chemical bonds between atoms resulting in new substances
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12
Q

Example of chemical change

A

Hydrogen is burned as fuel in the space shuttle’s engine

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13
Q

Nuclear Change

A
  • Change in the protons or neutrons in an atom resulting in a new atom
  • Most energy
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14
Q

Example of nuclear change

A
  • Hydrogen undergoes nuclear fusion in the sun
  • Produces helium
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15
Q

What is a System?

A

The substance undergoing a change

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16
Q

What are the surroundings?

A
  • Describes the system’s environment
  • Includes all matter that is not part of the system
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17
Q

What is thermal energy?

A
  • Total amount of movement (kinetic energy) of the particles in a system and the stored energy within these particles (potential energy)
18
Q

What does thermal energy depend on?

A
  • How many particles are moving and their temperature
19
Q

What is temperature?

A
  • Measures the average speed of particles in a sample
  • Measured in ℃ or K
20
Q

What is heat?

A
  • The amount of thermal energy transferred between substances
  • Due to a temperature difference
  • Measured in Joules (J)
21
Q

Extensive Property

A
  • Directly depends upon the amount of substance
22
Q

Example of an extensive property

A

Heat

23
Q

Intensive Property

A
  • Not related to the amount of the substance
24
Q

Example of an intensive property

A

Temperature

25
Q

State Function

A

Property that depends only on its current state and not on how that state was reached

26
Q

Exothermic - Thermal energy (q)

A

Released

27
Q

Exothermic - Direction of the flow of heat

A

System —> Surroundings

28
Q

Exothermic - Temperature Change

A
  • Tf>Ti
  • ΔT>0
  • Postive
29
Q

Exothermic - Sign of ΔH

A
  • ΔH<0
  • Negative
30
Q

Exothermic - Energy Term

A
  • Product
  • A + B —> C + energy
31
Q

Endothermic - Thermal Energy (q)

A

Absorbed

32
Q

Endothermic - Direction of the flow of heat

A

Surroundings —> System

33
Q

Endothermic - Temperature Change

A
  • Tf<Ti
  • ΔT<0
  • Negative
34
Q

Endothermic - Sign of ΔH

A
  • ΔH>0
  • Postive
35
Q

Endothermic - Energy Term

A
  • Reactant
  • A + Energy —> B + C
36
Q

Open System

A
  • Both matter and energy can move between the system and the surroundings
37
Q

Open System Example

A

Boiling pot of water

38
Q

Closed System

A

Can exchange energy but not matter with its surroundings

39
Q

Closed System Example

A

Covered pot of water

40
Q

Isolated System

A
  • Neither energy nor matter can move into or out of the system
  • Will still be some energy loss
41
Q

Isolated System Example

A

Insulated thermos