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Flashcards in Foam Concentrate Technology Deck (45)
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1

The resulting finished foam ...

... extinguishes and/or prevents fire by the following methods:
Separating - Creates a barrier between the fuel and burning vapors
Cooling - Lowers the temperature of the fuel and adjacent surfaces
Suppressing - (sometimes referred to as smothering) Prevents the release of additional flammable vapors, access to oxygen in the atmosphere, and therefore reduces the possibility of ignition of resignation

2

As water in the finished foam blanket ...

... releases (drains), the foam blanket becomes less effective as a vapor barrier and/or heat shield.
The rate at which a foam blanket reduces in effectiveness is proportional to the rate at which its water drains.

3

Mechanical type foam concentrates ...

... in use today must be proportioned (mixed with water) and aerated (mixed w/air) before they can be used

4

Foam Concentrate

Liquid found in a foam storage container before the introduction of water

5

Foam Solution

Mixture in the proper ratio of foam concentrate and water before the introduction of air

6

Foam Proportioner

Device that mixes foam concentrate in the proper ratio w/water

7

Finished Foam

Completed product after air is introduced into the foam solution and after it leaves the nozzle or aerator

8

Class B foam concentrates ...

... designed solely for hydrocarbon fires (such as regular fluoroprotein and regular AFFF) will NOT extinguish polar solvent (alcohol type fuel) fires regardless of the concentration at which they are used

However, foam concentrates that are intended for polar solvents may be used on hydrocarbon fires

9

Foam expansion ...

... refers to the increase in volume of a foam solution when it is aerated

10

Low Expansion Foam

Air/solution ratio up to 20 parts finished foam for every part of foam solution (20:1)

11

Medium Expansion Foam

Most commonly used at the rate of 20:1 to 200:1 through hydraulically operated nozzle style delivery devices

12

High Expansion Foam

Rate is 200:1 to 1,000:1

13

Freezing and thawing ...

... shall have no effect on UL listed foam concentrate performance

14

Compatibility w/Other Extinguishing Agents

AFFF, FFFP, and fluoroprotein foams are all compatible w/carbon dioxide, halon substitutes, and dry chemical agents and may be simultaneously discharged w/them
Also known as Multi-agent attack

15

Class A foam concentrates require ...

... U. S. Forest Service approvals from the U. S. Department of Agriculture

16

Foam Drainage

A short drain time means that the foam blanket holds water and provides an insulating foam layer for an extended period before the water releases

17

Elements affecting the drainage process

- Fuel temp
- Heat of the fire
- Size of the flame front
- Ambient air temp
- Wind

18

Foam Concentrate Types

Some foam concentrates are thick and viscous. These concentrates are typically AR-AFFF, 3% to 6% or 1% to 3% and produce finished foam that can form tough, heat resistant blankets that drain slowly when proportioned at higher ratios of water and concentrate

Thinner concentrates are generally found in the nonalcohol-resistant (AFFF, FFFP, and fluoroprotein foam) or Class A Foam

19

High Expansion Foam Concentrates

Used from 1% to 2.5% concentrations to produce large volumes or finished foam for flooding confined spaces

20

Class A Foam Concentrates

Wetting agents (non foaming, ionic, and nonionic surfactants) added to water will improve its absorption into Class A materials.

Class A foam concentrate is a formulation of hydrocarbon surfactants. The ionic and nonionic surfactants help reduce water's surface tension in the foam solution

21

Reducing water's surface tension ...

... provides better fuel penetration of the water, thereby increasing its effectiveness

22

Surface Tension Reduction

The effect of a surfactant on the water/concentrate foam solution allows water to spread more rapidly over the surface of Class A fuels and penetrate organic fuels

23

Expansion

Aeration of the water/concentrate foam solution into a volume of bubbles that is greater than the volume of the solution.
Water quality, aeration method( (nozzle, compressed air, airdrop altitude), concentrate ratio, and concentrate formulation all affect the obtainable expansion ratio

24

Drainage

Amount of liquid that drains from the bubble mass to wet and/or penetrate the Class A fuel is affected by the expansion ratio

25

Consistency

Small bubbles of a consistent size are best for the development of long lasting finished Class A foam that can adhere to surfaces (horizontal, vertical, and overhead)

Large bubbles tend to break down more rapidly and release more liquid to wet and and penetrate Class A fuels

Class A foam does not adhere to hot, vertical fuel surfaces that are in excess of 212 degrees F

26

Retention

Characteristic of Class A foam to remain on and in the fuel, reduce the fuel temp, and increase the fuel moisture content.
*Air temp, wind movement, fuel's latent heat, and the amount of heat present affect retention time

27

Viscosity

Refers to a liquid's thickness or ability to flow.
High viscous liquid concentrates are very thick and may be difficult to proportion through some types of foam concentrate pumps.
Low viscosity are very thin and pour easily.
Temperatures affect viscosity. Class A foam concentrates become more viscous when cold and less viscous when heated

28

Proportioning

Class A foam drain times increase w/an increase in the proportioning ratio.
A rich concentrate/water mix ratio (using a higher proportion of foam concentrate than normal) produces thicker, richer foam that drains slower than a lean ratio (using a lower proportion of foam concentrate than normal)

29

Most foam nozzles ...

... produce more stable finished foams at a 1% concentration than they do at 0.4% to 0.5% concentrations

*Greater than 0.5% w/standard fog nozzles does not appear to increase fire-fighting performance

30

Fire Attack and Overhaul w/Standard Fog Nozzles

0.2% to 0.5% foam concentrate

31

Exposure Protection w/Standard Fog Nozzles

0.5% to 1% foam concentrate

32

Most Operations w/Air Aspirating Foam Nozzles

0.3% to 1% foam concentrate

33

Most Operations w/Compressed Air Foam System

0.2% to 0.5% foam concentrate

34

Class B foam concentrates ...

... are manufactured from either a synthetic or protein base.
Protein base are derived from animal protein
Synthetic is derived from fluorosurfactants

35

Degredation

Protein based foam degrade in 2 to 8 days
Synthetic degrade in 20 to 40 days

36

Effective Class B Characteristics

- Water retention
- Finished Foam Life
- Heat Resistance
- Multipurpose Use
- Viscosity
- Knockdown Speed and Flow Characteristics
- Fuel Resistance
- Vapor Suppression
- Alcohol Resistance
- Quarter Life

*Most finished foam breaks down near or over 212 degrees F
**May become ineffective at fuel temps near or over 150 degrees F
***Polar solvent fuels (alcohols, ketones, and esters) are mixable (miscible) w/water

37

Class B Proportioning

Hydrocarbons - 3% (3:97 ratio)
Polar Solvents - 6% (6:94 ratio)

High expansion foams are used between 1% to 2.5%

38

Once the fire is extinguished ...

... finished foam consumption is only effected by the latent heat of the fuel, weather conditions, and finished foam's natural drainage rate

39

Regular Protein Foam

Concentrate is derived from naturally occurring sources of protein such as hoof, horn, or feather meal

40

Fluoroprotein Foam

Concentrates are oleophobic (oil shedding) and well suited for sub-surface injection: a process by which foam solution is pumped into the bottom of a burning petroleum tank and then floats to the top to form a fire extinguishing foam blanket

41

Fluoroprotein foam concentrates ...

... can be formulated to be alcohol resistant by adding ammonia salts that are suspended in organic solvents. Alcohol resistant fluoroprotein foam concentrate maintains its alcohol resistive properties for about 15 min

42

AFFF

Is the most commonly used foam concentration today
AFFF is completely synthetic. It consists of fluorochemicals and hydrocarbon surfactants combined w/high boiling point solvents and water

43

When AFFF/FFFP is applied to a hydrocarbon fire ...

- Air/vapor excluding film is released ahead of the foam blanket
- Fast moving foam blanket moves across the surface and around objects, adding further insulation
- As the aerated (7:1 to 20:1) foam blanket continues to drain its water, more film is released giving finished foam the ability to "heal" over areas where foam blankets are disturbed

44

Emulsifiers

Are designed to mix with the fuel, breaking it into small droplets and encapsulating them. The resulting emulsion is rendered nonflammable

45

4 Basic Proportioning Methods

Eduction (induction) - Uses a foam eductor, inductor, line proportioner, or ratio controller

Injection - Uses a foam concentrate pump or bladder proportioner to pump foam concentrate at the appropriate ratio into a water stream

Batch Mixing - Uses a "dump and pump" or one time use process

Premixing - Stores in a solution (such as in a fire extinguisher) ready to use