Gas Pressure Flashcards
(18 cards)
1 standard atmospheres (atm) = (mm Hg & bar)
760mm Hg = 101.3 kPa & 1.01325 bar
Pressure
The force exerted on an object divided by the area over which it is exerted. Barometer measures pressure. Unit in millimeters of mercury.
SI unit of pressure is the _______
pascal (Pa)
1 pascal (Pa) =
1 newton/meter2
1 bar = (Pa & atm)
100,000 Pa 0.9872 atm
Boyle’s law
Expresses that the product of the pressure and volume of a gas sample is a constant at a given temperature. P1V1 = P2V2 at constant n and T
Avogadro’s Hypothesis
Equal volumes of gases under the same condition of temperature and pressure have equal number of particles. V ⇒n at constant T and P
The Ideal Gas Law
PV=nRT
Standard temperature and pressure (STP)
Gas temp of 0º or 273.15K Pressure of 1 atm
Standard molar volume
1 mol of an ideal gas occupies 22.414 L
Gas constant R
0.082057 L•atm/ K•mol
Density of Gas
d = m/V = P•M/R•T
Dalton’s law of partial pressures
Ptotal = P1 + P2 + P3 . . .
General Gass Law
P1 V1/T1 = P2V2/T2
Temp in K (Cº +273)
Normal Boiling point
The temperature at which the vapor pressure of a liquid equals 1 atm
Rate of effusion of Gas 1/
rate of effucion of gas 2 =
Sq Root ( molar mass gas 2/ molar mass gas 1)
Properties of Water that are contributed to hydrogen bonding
High melting point
high heat of vaporization
low vapor pressure
high suface tention
Hydrogen bonding, X—H . . . :Y
Very polar X—H bond and atom Y with lone pair of electrons (where X and Y = F, N, O). Typical energy =
20 kJ/mol.