GB1: Chapter 2 Flashcards

(48 cards)

1
Q

Atomic nucleus

A

protons and neutrons packed tightly at center of atom, is + charged due to protons

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2
Q

common elements of human body

A

carbon, nitrogen, hydrogen, oxygen, potassium, phosphorus, magnesium, calcium, chlorine, sodium, sulfur

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3
Q

compound

A

2 or more elements combined in fixed ratio

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4
Q

electron cloud

A

electrons rapidly move about the nucleus, forming a cloud of - charge

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5
Q

Electron orbitals

A

3D space where electron is found 90% of the time
No more than 2 electrons occupy single orbital

In 2nd energy shell, 4 orbitals can hold up to 8 electrons (2s & 2p = 8 electron spaces)

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6
Q

electron shell

A

fixed energy shell, electron’s state of potential energy

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7
Q

electrons absorb/gain energy:
electrons lose energy:
the amount of energy gained/lost:

A

increase in energy level (further away from nucleus)

decrease in energy level (closer to nucleus)

equals the amount of energy between shells

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8
Q

elements

A

pure substances, cannot be broken down into other substances

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9
Q

energy

A

capacity to cause change

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10
Q

every electron shell has electrons at certain energy level that are distributed among…?

A

specific number of orbitals of certain size and orientation

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11
Q

how does atom stay together?

A

attraction between the +charged nucleus and -charged electrons

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12
Q

in chemical rxns, what is involved?

A

valence electrons are directly involved, chemical bonds are being broken/formed

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13
Q

inert elements

A

chemically nonreactive elements that have complete valence shell

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14
Q

matter

A

anything that has mass and takes up space, made up of elements

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15
Q

molecules

A

2 or more atoms covalently bonded together

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16
Q

potential energy

A

energy that matter has due to its location or structure, energy locked into structure-not currently changing
matter naturally moves toward the lowest possible state of potential energy (nelsen’s law #2!)

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17
Q

subatomic particles

A

these make up an atom
proton +
neutron no charge
electron -

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18
Q

trace elements w/ example

A

elements required by organisms in minute quantities (less than 0.01% mass) ex: fluorine, boron

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19
Q

valence shell, what does it determine?

A

outermost shell of electron, it determines the chemical behavior of atom

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20
Q

atomic number

A

of protons

of protons = # of electrons in neutral atom

21
Q

Atomic mass (3)

A

atom’s total mass, weighted average of isotopes, can be estimated by mass number (# protons + # neutrons)

change in proton # = different element
change in neutron # = isotope of element

unit of measurement is DALTONS

22
Q

isotopes

A

Atoms of element that have different number of neutrons (different atomic masses)

23
Q

radioactive isotopes

A

nucleus decays spontaneously and gives off particles and energy. unstable, so goes to lowest energy level for stability - nelsen’s law #2!
when this changes the # of protons, atom changes to different element

Parent isotope decays into its daughter isotope at fixed rate

24
Q

radioactive tracers

A

diagnostic tools in medicine: radioactive isotopes are incorporated into biologically active molecules used as tracers to track atoms during metabolism
also used with sophisticated imaging instruments

25
half-life
time it takes for 50% of parent isotope to decay
26
radiometric dating
process to measure ratio of different isotopes and calculate how many half lives have passed since organism was fossilized/rock was formed
27
chemical bonds w/ 5 types
attraction between atoms with incomplete valence shells through transfer or sharing of electron(s) single, double, triple: increase in bond # = decrease in bond length = more energy in bonds van der waals hydrogen bonds ionic bonds polar covalent bonds nonpolar covalent bonds
28
bonding capacity
atom's valence, maximum # of bonds that atom can form with other atoms to complete octet, corresponds to # of electrons needed to complete valence shell octet
29
covalent bond
the sharing of a pair of electrons between 2 atoms
30
nonpolar covalent bonds
EQUAL sharing of pair of electrons between 2 atoms due to relatively equal values in electronegativity
31
polar covalent bonds
UNEQUAL sharing of pair of electrons between 2 atoms due to large difference in electronegativity, resulting in partial charges (more EN, negative partial charge; less EN, positive partial charge)
32
electronegativity
attraction of particular atom for electron in covalent bond more EN = stronger pull of electrons
33
ionic bonds
bond formation due to ATTRACTION between cation (+charged ion) and anion (-charged ion) because of complete transfer of valence electron(s) from one atom to another (this is due to the extremely great difference in electronegativity) compounds formed: salts, ionic compounds in 3D lattice
34
hydrogen bonds
weaker chemical interaction, hydrogen atom that is covalently bonded to an electronegative atom (giving it partially +charge) is ALSO ATTRACTED to another electronegative atom (with partial -charge) in cells, usually to oxygen or nitrogen
35
chemical behavior of atom
determined by distribution of electrons in shells, especially in outer shell atoms with same number of valence shells exhibit similar chemical behaviors
36
van der waals interactions
weakest interaction; only occurs when atoms and molecules are close together, due to the partially negative positive and negative parts of atom/molecule as electrons aren’t always evenly distributed
37
molecular shape
depends on position of atom's orbitals. size/shape are what determine molecule's function and how they interact with each other
38
hybridization
when atom forms COVALENT BONDS, the orbitals in its valence shell undergo rearrangement 1s + 3p of valence shell in covalent bond = 4 hybrid orbitals in teardrop shapes
39
morphine vs endorphine
have similar effects due to similar molecular structures as they bind to same receptor in brain
40
chemical equilibrium
DYNAMIC EQUILIBRIUM forward/reverse rxns occur at same rate, relative concentrations of reactant/product don't change more reactant-> produce more products More product -> produce more reactants
41
orbitals, electron configuration
electrons occupy opposite regions of atom (because they repel each other) electron spins must be opposite of each other electron configuration shows how electrons are distributed in orbitals
42
reactivity of atom
due to the unpaired electrons in one or more orbitals in valence shell
43
1s___
1s = orbital 1 = energy shell s = determines orbital's shape s = sphere p = propellor
44
chemical reactions
forming/breaking chemical bonds leading to change in composition of matter all are theoretically reversible
45
polar covalent bond value
0.4 < EN < 0.7
46
nonpolar covalent bond value
EN < 0.4
47
ionic bond value
EN > 1.7
48