General Chemistry Flashcards

(38 cards)

1
Q

Combustion reaction

A

Hydrocarbon or alcohol reacts with O2 to form CO2 and H2O

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2
Q

Cohesion in measuring tool

A

Molecules of liquid stick to each other - forming convex meniscus

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3
Q

Adhesion in measuring tool

A

Molecules of liquid stick to glass of tool - forming a concave meniscus

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4
Q

Neutralization problems

A

n1M1V1 = n2M2V2

n - is normality. How many equivalents of H+ and OH- there are…

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5
Q

Bond strength decreases…

A

…as the difference in electronegativity increases

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6
Q

A stronger acid has…

A

Weak bond strength

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7
Q

Bond dissociation energies are always…

A

Positive

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8
Q

Half life for 1st order reaction

A

t(1/2) = 0.693/k

k - is the rate constant

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9
Q

Accuracy

A

Measurement is close to true value

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10
Q

Precision

A

Measurement is consistent

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11
Q

Good electrolytes

A

Strong acids, strong bases, ionic compounds

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12
Q

Best definition of boiling point

A

Temp when VP of liquid equals surrounding pressure

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13
Q

Volatility

A

Ability for liquid to evaporate

More volatile=weak IMF’s

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14
Q

[H+] for weak acids…

A

=sqrt(Ka x M)

**also for OH-, just with Kb

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15
Q

Reacting a hydrocarbon with oxygen produces…

A

H20 and CO2

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16
Q

0th law of thermodynamics…

A

Two systems are in equilibrium with a third…then they are all in equilibrium with each other

17
Q

Work eqn at constant pressure (isobaric)…

18
Q

Henry’s Law (solubility of a gas)

A

C=kP

C - cons of a gas in soln
P - partial pressure of gas above soln

19
Q

Non state functions

A

Heat and work

20
Q

Zero order reaction

A

Slope=-k

Plot is conc vs time

21
Q

1st order reaction

A

Slope=-k

Plot is ln(conc) vs time

22
Q

2nd order rxn

A

Slope = k

1/conc vs time

23
Q

Which elements react violently with pure oxygen?

A

Group 1 and 2 metals

Group 1 alkali react more violent than group 2alkaline earth metals

24
Q

Nuclear binding energy

A

Energy needed to split the nucleus

25
Boyles law
P1V1 = P2V2
26
Charles Law
V1/T1 = V2/T2
27
Allotrope
Different structural forms of the same element
28
Gas solubility increases when...
Pressure increases Temperature decreases
29
7 diatomic molecules Never have fear of ice cold beer
``` Nitrogen Hydrogen Fluorine Oxygen Iodine Chlorine Bromine ```
30
Bond energies
Bonds broken - bonds formed
31
Isoelectronic
Same amount of valence electrons
32
Vacuum filtrations
Technique that separates particles based on charge
33
Diamagnetism
Repels magnetic fields
34
Paramagnetism
Attracts magnetic fields
35
Atoms charge goes down
Reduced
36
Atoms charge goes up
Oxidized
37
Lower Rf
More polar
38
Higher Rf
Less polar