group 7, halogens Flashcards

1
Q

flourine gas colour?

A

pale yellow gas

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2
Q

chlorine gas colour

A

pale green gas

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3
Q

bromine colour

A

brown-orange liquid

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4
Q

iodine colour

A

grey solid

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5
Q

explain the trend of boiling point going down group 7

A

the boiling point increases going down the group. This is because VDW forces increase due to the increasing size and relative mass of the atoms. as you go down the group the physical state goes from gas at the top of group 7 to solid at the bottom

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6
Q

explain the trend of electronegativity going down group 7?

A

decreases as we go down the group. electro negavity is the abiltiy of an atom to attract a shared pair of electrons (towards itself) in a covalent bond. The atom gets larger and the distance between the postiive nucleus and bonding electrons increases. hence there is more shielding.

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7
Q

reativity trend down group 7?

A

decreases.

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8
Q

for a reaction to occur, what must happen?

A

an electron is gained

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9
Q

atoms with a smaller radius, do what better than larger atoms?

A

attract electrons better than larger atoms.

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10
Q

more reactive halogens will _____ less reactive halide ions

A

displace

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11
Q

in terms of being oxiding. what trend is that going down g7

A

halogens are less oxidising going down the group

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12
Q

A HALOGEN WILL DIPLACE A HALIDE FROM SOLUTION IF WHAT?

A

THE HALIDE IS LOWER IN THE PERIODIC TABLE.

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13
Q

show some reaction of halogens with halide ions?

A

https://merchanttaylorsschools-my.sharepoint.com/:w:/g/personal/tofoma_merchanttaylors_com/EfmDeqK3cdBKiOGqR0zoWh4BGSAI05I3riylpkuLfP6WXA?e=FZFj3y

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14
Q

what reaction is bleach made in?

A

via a disproportionation reaction

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15
Q

bleach consists of ….

A

mixing chlorine with sodium hydroxide to form sodium chlorate (I) solution.known as bleach

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16
Q

in the reaction to form bleach, why is it named a disproportionation reaction. (give the reaction)

A

https://merchanttaylorsschools-my.sharepoint.com/:w:/g/personal/tofoma_merchanttaylors_com/Eco0dbNfB_hLn16UeYvvmlwBBGIU1wIXYRVI1hRXGEDKAQ?e=XgMJh3

17
Q

uses of sodium chlorate (I) i.e bleach?

A

treating water
bleaching papers and fabrics (making them witer)
cleaning agents (bleach)

18
Q

adding chlorine to water can ___ bacteria in water

19
Q

adding water to chlorine will produce what type of ions which can do what.

A

adding water to chlorine will produce chlorate (I) ions (CLO-) which kill bacteria. useful in drinking water and pools

20
Q

show the disproptionation reaction of h20 + cl2 and state why its a disproportionation reaction

A

https://merchanttaylorsschools-my.sharepoint.com/:w:/g/personal/tofoma_merchanttaylors_com/ER26-VHOJp9KkPhIsuefB8UBBx-yw7ECMWP8mTYdRngsbg?e=UKqH9J

21
Q

give the reaction for when water reaction with cl2 in the presence of sunlight can state what this sunlight does and what that leads to in terms of killing the bactiera in water?

A

https://merchanttaylorsschools-my.sharepoint.com/:w:/g/personal/tofoma_merchanttaylors_com/EVhLeXdybhNKsP1QDjTTLP8BndlmB9GK6emxbHMcMGKPmQ?e=IwKzaB

22
Q

ADVS and disadvs OF CHLORINATING DRINKING WATER?

A

https://merchanttaylorsschools-my.sharepoint.com/:w:/g/personal/tofoma_merchanttaylors_com/EfY6AFJys2lJm59F0EIcBCUBEXQ8VJPLBho8TSFZURm7qw?e=Fv1e8Q

23
Q

HALIDE IONS LOSE AN ELECTRON IN REACTIONS, so they are what type fo agents?

A

reducing agents

24
Q

GIVE THE TRENT OF THE REDUCING POWER OF HALIDE IONS GOING DOWN THE GROUP, and give the name of the 2 tests to prove this trend?

A

https://merchanttaylorsschools-my.sharepoint.com/:w:/g/personal/tofoma_merchanttaylors_com/EW2OKJsqgMJEs6AAaGEuutgBPgojbmau9tzhoFcTlojZHA?e=kkXmRD

25
How do halide ions react with concentrated sulfuric acid, and how do the reactions vary between Cl⁻, Br⁻, and I⁻?
https://merchanttaylorsschools-my.sharepoint.com/:w:/g/personal/tofoma_merchanttaylors_com/EZb70YdFkvREhRic_LEEbuUBHX07RSmOQaHL3N8t6BldTQ?e=tBGZqF IMPORTANT TO NOTE THAT DEPENDING ON THE HALIDE ION, H2SO4 GETS REDUCED TO SO2, S AND H2S. FOR EG WITH BR2 IT GETS REDUCED TO SO2. WITH I2 IT GETS REDUCED TO S, AND FURTHER GETS REDUCED TO H2S. THESE ARE ALL THE REDUCTION PRODUCTS SHOWING THE REDUCING POWER OF THE HALIDE ION, IODINE BEING THE STRONGEST. (with chlorine nacl+h2so4 gives nahso4 + hcl thats it)
26
How do you test for halide ions using silver nitrate, what colours indicate each halide, why is nitric acid used, and how does ammonia help confirm the result?
https://merchanttaylorsschools-my.sharepoint.com/:w:/g/personal/tofoma_merchanttaylors_com/EanVgu4ApLpIt_8nsQQa4vcBRttGfRTdTdh2atuW8jtgZA?e=TMqGx9
27
what are the colours given in the flame test involving ca2+, Sr2+ and Ba2+.
ca2+ - dark red Sr2+ - Red Ba2+ - green
28
how do u test for ammonium compounds, and given the overall reaction.
add sodium hydroxide (NaOH), gently heat and if ammonium compound is present, ammonia gas will be produced. to test for that ammonia use damp red litmus paper. ammonia will dissolve in the water and turn litmus paper blue if its present. NH4+ (aq) + OH- (aq) ------> NH3 (g) + H2o(l)
29
how do u test for hydroxide ions?
hydroxides are alkaline and they will turn red litmus blue. this test doesnt mean u will definitely have hydroxides. red litmus turns blue for any alkali. further tests are needed to confirm u have a hydroxide
30
how do u test for carbonates?
ADD HCL, if carbonates present CO2 is produced. Co2 is then bubbled through limewater, and limewater turns cloudy.
31
testing for sulfates and give the ionic equation
add hcl to remove any carbonates in. (the reason is is that these could ppt out after addium barium chrloride giving a flase result). ADD BARIUM CHORIDE white ppt of barium sulfate forms if sulfate is present. - this is insoluble Ba2+(Aq) + so4 2- (AQ) -----> BAso4 (s)
32