haloalkanes Flashcards
(9 cards)
what are haloalkanes
halogen that takes place of a h atom in an alkane
what is a free radical
a reactive species which possess as unpaired electron
what is free-radical substitution reaction
- initiation
- propagation
- termination
what do u do in initiation step
break the halogen bond using an UV light to produce 2 radicals in a homolytic fission reaction
what do u do in the propagation step
the progression of a substitution reaction
termination
when the chain terminates due to 2 free radicals reacting together and forming a single unreactive molecule
nucleophile
why is ultraviolet needed
provides energy to break (covalent) bond in chlorine
1,1,2-trichloro-1,2,2-trifluoroethane is banned for damaging the ozone layer.
3 equations to show how it’s involved in damaging the ozone layer
INITIATION CCL2FCCLF2 -> Cl* + CCl2FCF2
Cl* + O3 -> ClO* + O2
ClO + O3 -> Cl* + 2O2