halogens Flashcards

1
Q

what is the trend in bp and mp of halogens and why

A

bp and mp increases down the group as theres more electrons so stronger london forces which requires more energy to break them

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2
Q

state and colour of halogens at room temp

A

fluorine- pale yellow gas
chlorine- pale green gas
bromine- red-brown liquid
iodine- grey solid

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3
Q

state colour of halogen in aqueous solution of water

A

chlorine- pale green solution
bromine- yellow solution
iodine- brown solution

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4
Q

what is a halide

A

a binary compound of a halogen

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5
Q

why must experients with halogen be done in a well ventilated area

A

they are powerful oxidising agents and toxic

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6
Q

what is the trend in reactivity down group 7

A

reactivity decreases as
atomic radius increases
sheilding increases
nucleur charge increases but doesnt outweigh the effect of increase in sheliding and atomic radius
therefore halogen become weaker oxidising agents down the group

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7
Q

what will the halogens look like when cyclohexane is added

A

chlorine- pale green
bromine- yellow
iodine- violet

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8
Q

whaf is displacement of group 7 elements

A

more reactive halogen displacing less reactive halide fron it’s aqueous solution

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9
Q

what is disproportionation and what can it happen with

A

a reaction where the same element is both oxided and reduced

any halogen except fluroine as its a powerful oxidising agent

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10
Q

how does chlorine react with water

A

Cl2(g) + H20(l) —> HCI(aq)+ HOCI(aq)

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11
Q

how is bleach formed, why this way and what is used as bleach

A

by reacting chlorine with cold dilute sodium hydroxide solution as it has a high solubility

Cl2(aq) + 2NaOH(aq) —> NaCIO(aq) + NaCI(aq) + H20(l)

The mixture of NaCIO is used as bleach. The NaCIO is just called sodium chlorate (1).

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12
Q

give 1 pro and 1 con of adding chlorine to water

A

it kills bacteria

it could form chlorinated hydrocarbons which are toxic and carcinogenic

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13
Q

why will chlorine and water bleach universal indicator

A

the ClO- ion fron HOCl produced is a powerful oxidising agent

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