Hydrogels and Advanced Formulations Flashcards
(23 cards)
Hydrogel characteristics
3D, hydrophilic cross-linked polymer network. Hold lots of water, behave like liquid and solid
Ideal hydrogel
Absorbency, low soluble, low residual, cheap, durable, stable, biodegradable, photo stable, neutral pH, re-wettable
Hydrogel classifications
Preparation, cross-linking, source, charge, response, physical aspect, structure, degradability
Preparation types of hydrogels
Interpenetrating network, homopolymer, co polymer
IP hydrogels
homo and copolymers combined with cross linking agent
Homopolymer
made of singular type of monomer
Copolymer
made of multiple different types of monomers
Cross-linking types of hydrogels
physical or chemical
Physical cross-linking
intermolecular forces, H-bonding or ionic bonds hold together. Weaker, reversible, less stable
Chemical cross-linking
bonded covalently. Stronger, irreversible, stable, require initiator
Charge types of hydrogels
anionic, cationic, amphoteric, nonionic
Response types of hydrogels
chemical, physical, biochemical
Structural types of hydrogels
amorphous, semi-crystalline
Physical aspect types of hydrogels
gel and film, matrix, particles
Types of hydrogel synthesis
bulk, suspension, photo, solution
Bulk polymerisation
simple and pure, pure monomer and initiator, no solvent, few additives. hard to temp control
Suspension polymerisation
monomer and initiator mix dropped into solvent and forms beads suspended in solvent
Photo polymerisation
in situ, light induced polymers. Initiator is light sensitive. Used in 3D printing
Solution polymerisation
ionic or neutral monomers mixed into solvent and cross linker, initiated with UV.
Hydrogel applications
nappies, breast implants, cell technology, face masks
Additive manufacturing
3D printing where objects are formed from depositing, joining or solidifying materials under computer control
SLA
stereolithography 3D printing using photo polymerisation
FDM
fused deposition model, layers of plastic form object