hydrogen, nitrogen and ammonia Flashcards

(47 cards)

1
Q

list the properties of hydrogen

A

lightest element
colourless and odourless
more reactive than copper
oxygen and hydrogen will explode when lit

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2
Q

why is there no hydrogen in air

A

bc its so light it escapes earth’s atmosphere

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3
Q

what is the properties of nitrogen

A

colourless, odourless, unreactive gas
use for protein and growth
slighly soluble in water
very inreactive

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4
Q

what is the most and second most mamufactured chemical

A

sulfuric acid and ammonia

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5
Q

what is the characteristic of ammonia

A

colourless with strong smell
less dense than air
turns red litmus blue

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6
Q

describe the Haber process

A
  1. nitrogen is obtained from air and hydrogen is obtained by reacting a natural gas with steam
  2. gas mixture is compressed. more and more gas is pumped in until the pressure reaches 200 atmospheres
  3. compressed gas flows to converter
  4. mixture is cooled and ammonia condense to liquid
  5. ammonia is stored in a tank as liquid under pressure
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7
Q

what is the equation for ammonia

A

N2 + 3H2–> 2NH3

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8
Q

why is nitrogen and hydrogen recycled to the converter

A

bc only 15% of the mixture leaving is ammonia

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9
Q

how do we obtain nitogen to make ammonia and the equation

A

air is 80% nitrogen so oxygen is removed by burning oxygen

2H2 + o2 –> 2H2O

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10
Q

where is the energy used to make ammonia from

A

the heat given out in the reaction from oxygen and hydrogen

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11
Q

how is hydrogen obtained for ammonia and their equation

A

hydrogen is made by reacting natural gas with steam
CH4 + 2H2o –> [catalyst] CO2 + 4H2
or cracking hydrocarbons from petroleum
C2H6 –> [catalyst] Co2 + 4H2

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12
Q

what is the conditions to make ammonia

A

400 C and 200 atmospheres

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13
Q

why is the temp to make atmosphere not 350 or 450

A

bc 350 is too slow and 450 wld need very powerful pumps so expensive

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14
Q

what is used as a catalyst for ammonia

A

iron

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15
Q

what do plants use nitrogen for

A

making chlorophyll and proteins

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16
Q

what do plants use potassium for

A

produce proteins and resist disease

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17
Q

what does plants use for phosphorus

A

helps root grow and crops ripen

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18
Q

what is a fertiliser

A

any substance added to soil to make it more fertile

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19
Q

what is an example of natural fertiliser

A

animal manure

20
Q

what is synthetic fertiliser

A

fertilisers made in factories

21
Q

what is the formula for ammonium nitrate

22
Q

what is the formula for pottasium sulfate

23
Q

what is the formula for ammonium phosphate

24
Q

what is the formula for ammonia sulfates

25
what is the consequences of fertilisers
in rivers: algae bloom - algae grows and cover water when they die bacteria feed on them and uses up all oxygen - fish suffocate water supply: nitrate ions can end up in water -converted to nitrate ions in body and binds to haemoglobin so less oxygen carried -cause illness to infants causing skin to be blue
26
where is sulfur found
element in underground beds occurs as a compound in many metals ores like lead ore galena sulfur compound also occur naturally in fossil fuel
27
what are the 2 ways to extract sulfur
oil and gas | sulfur beds
28
how do we extract sulfur from oil and gas
obtained from petroleum or natural gas hydrogen sulfide in methane is separate and reactede with oxygen to give sulfur 2H2S + O2 --> 2S + 2H2O
29
how is sulfur obtained from sulfur beds
undeground sulfure beds | superheated water is pumped down to melt the sulfur and carry it to the surface
30
what are the properties of sulfur
brittle yellow solid molecular and has low mp insoluble in water react with metal to form sulfides
31
what are the 2 different forms of sulfur
rhombic and monoclinic sulfur
32
what are the uses of sulfur
``` make sulfuric acid added to rubber to toughen it making drugs, pesticides, dyes, matches and paper cosmetic, shampoo and body lotion added to cement to make sulfur concrete ```
33
what is the properties of sulfur dioxide
``` forms when sulfur is burned in air colourless gas heavier than air with chocking smell acts as a blech when damp or in a solution kills bacteria ```
34
what are the uses of sulfur dioxide
make sulfuric acid bleach wool, silk and wood pulp food preservatives stops growth of bacteria and moulds
35
how is sulfuric acid made
1. sulfur is burned in air 2. it is mixed with air to from sulfur dioxide - s+0-->SO2 3. it is passed over 4 separate beads of catalysts at 450 C - 2SO2 + O2 2SO3 4. sulfur trioxide dissolved in concentrated sulfuric acid to form oleum 5. mixed with water to from sulfuric acid - H2) + S03 --> H2SO4
36
what is used as a catalyst in contact process
pellets of vanadium V oxide
37
why is the mixture passed over 4 separate bed of catalyst in the contact process
to give reactant to further chances to react
38
how to increase the yield of sulfuric acid
sulfur trioxide is removed in the last 2 beds of catalysts | increase pressure by less than 2 atmospheres
39
why is sulfur trioxide dissolved in concentrated acid and not water
it wld form a thick dangerous mist of acid
40
how is the temperature of sulfur trioxide maintained
pipes of cold water are coiled ard the catalyst beds to carry heat away the hat makes water boil and steam is used to generate electricity for plant ro heating building
41
what min temp does the catalyst works at for contact process
above 400
42
what are the uses of sulfuric acid
fertilisers paints, pigments and dyestuff fibres and plastics soaps and detergents and car batteries
43
how is dilute sulfuric acid made
adding concentrated acid to water not by added water to acid bc heat wld be produced
44
what is a dehydrating agent
removes water
45
true or false: sulfuric acid is not a dehydrating agent
false
46
what does acid + metal give
salt + hydrogen
47
what does acid + metal oxide or hydroxide gives
salt + water