Introduction Flashcards

1
Q

It is a measurement science consisting of a set of powerful ideas and methods that are useful in all fields of science and medicine

A

Analytical Chemistry

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2
Q

Reveals the identity of elements and compounds in a sample

A

Qualitative

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3
Q

Indicates the amount of each substance in a sample

A

Quantitative

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4
Q

Components of a sample that are to be determined

A

Analytes

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5
Q

Results of a typical quantitative analysis are computed from two measurements:

A
  1. Mass or the volume

2. Quantity that is proportional

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6
Q

These are Quantity that is proportional

A

Mass, volume, intensity of light, electrical charge

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7
Q

Analytical method according to mass of the analyte or some compound chemically related to it

A

Gravimetric

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8
Q

Analytical method according to the nature of the volume of a solution containing suffcient reagent to react completely with the analyte

A

Volumetric Method

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9
Q

Analytical method which invloves electrical properties such as voltage, current, resistance and quantity of electrical charge

A

Electroanalytical methods

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10
Q

Analytical method that is based

Measurement of the interaction between electromagnetic radiation and analyte atoms

A

Spectroscopc Method

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11
Q

In the flow diagram showing the steps in a quantitative analysis:

What happens when the sample is soluble?

A

Proceed to the question: is it measurable property

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12
Q

In the flow diagram showing the steps in a quantitative analysis:

What should you do if the property of sample is measurable?

A

Eliminate interferences

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13
Q

In the flow diagram showing the steps in a quantitative analysis:

What should you do if the sample is not soluble ?

A

Carry out chemical dissolution

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14
Q

In the flow diagram showing the steps in a quantitative analysis:

What should you do after you carry out chemical dissolution?

A

Know whether is it a measurable property

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15
Q

In the flow diagram showing the steps in a quantitative analysis:

What should you do if the property of sample is not measurable?

A

Change the chemical form then eliminate the interferences

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16
Q

These are the first 3 steps in the flow diagram showing the steps in a quantitative analysis

A

Select method
Acquire sample
Process sample

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17
Q

It is the first question to be considered in the selection process of picking a method

A

Level of accuracy is required

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18
Q

In picking a method, It is the second consideration related to economic factors.

A

Number of samples to be analyzed

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19
Q

It influences the choice of method to some degree in picking a method

A

Complexity of the sample and the number of components in the sample

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20
Q

It invloves obtaining a small mass of material whose composition accurately represents the bulk of the material being sampled

A

Sampling

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21
Q

The most difficult step in an analysis and it is the source of greatest error

A

Sampling

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22
Q

A material is known as _________ if its constituent parts can be distinguished visually or the aid of a microscope

A

Heterogenous

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23
Q

It is the process of determining how much of a given sample is the material indicated by its name

A

Assay

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24
Q

We analyze________ and we determine _____________

A

Sample and substances

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25
No sample processing is required prior to the ______________ step
Measurement
26
We must process the sample in _______________ ways
Variety of different
27
A solid sample is _______ and ______ to ensure homogeneity
Ground and mixed
28
Sample should be ________for various length of time before analysis begins
Stored
29
Because of loss or gain of water it changes the composition of solids, it is a good idea to _______ samples before starting an analysis
Dry
30
The ___________of the sample can be determined at the time of the analysis in a separate analytical procedure
Moisture content
31
Liquid samples are subject to ______________
Solvent evaporation
32
If the analyte is a gas dissolved in liquid, analyte must be kept inside __________________ to prevent contamination by ___________________ gases
Second sealed, atmospheric
33
Extraordinary measures, including sample manipulation and measurement in an inert atmosphere, may be required to preserve the _____________ of the sample
Integrity
34
Portions of a material of approximately the same size carried through analytical procedure at the same time and same way
Replicate samples
35
Provides reliability of the experiment and it has atleast 3 same results
Replicate sample
36
Replication improves what?
Quality of result and reliability
37
How does a solvent disolve the entire sample including the analyte
Rapidly and completely
38
The sample may require ___________ with aquaous solution
Heating
39
It may be necessary to _______ the sample in all or oxygen to perform a high-temperature fusion of the sample in the presence of various fluxes
Ignite
40
Species other than the analyte that affect the final measurement is called?
Interferences or interferents
41
Species that cause an error in analysis by enhancing or attenuating the quantity being measured
Interference
42
Tecniques or reaction that work for only one analyte are said to be _________
Specific
43
Techniques or reactions that apply for only a few analytes are____________
Selective
44
It is all of the components in the sample containing analyte
Matrix or sample matrix
45
Measurement of the property is ___________ to the concentration
Directly proportional
46
Process of determining the proportionality between analyte concentration and a measured quantity
Calibration
47
Computing analyte concentrations are based on
Raw experimental data
48
Where can you collect raw experimental data?
Measurement step, instruments and stoichiometry of the reaction
49
The analytical results are incomplete without an estimate of ________
Reliability
50
Analytical results without an estimate of reliabilty is
No value
51
It is the first step in a feedback control system
Start control system
52
After you start the contro system what should you determine?
Desired state or the normal values
53
After you determine the desired state what should you do?
Measure the actual state
54
After measuring the actual state what should you do?
Display results
55
After displaying the results what should you do next?
Verify if the desired state actual
56
If the desired state is actual what shoul you do next?
Delay, try to make sure that it works
57
If the desired state is not actual what should you do?
Repeat the process and change control quantity
58
Process of continous measurement and control
Feedback system
59
Cycle of measurement, comparison and control
Feedback loop
60
Standardized system of unit
International System of Units (SI)
61
SI is the acronym for the french word?
Systeme international d’unites
62
This unit is widely used to express wavelength
Angstrom
63
Number of moles of solute species in one liter of solution
Molar concentration
64
Dimension of molarity
Mol L^-1
65
Gives the total number of moles of a solutein 1L of the solution
Analytical molarity
66
Express the molar concentration of a paricular species in a solution
Equilibrium molarity