Introduction Flashcards
(44 cards)
What elements are higher in living beings than in earth’s crust
Biomolecule’s definition
Earth crust descending order elements
Relative abundance of carbon and hydrogen
All the carbon compounds that we get from living tissue
O> Si > Ca >Na > Mg >H>C>S>N
Human element descending order
In dry weight animal cell
In dry weight plant cell
Most abundant organic compound in living organisms
O >C >H >N > Ca >S>Na >Mg >Si
Protein forms 60 - 70 % part
Carbohydrate forms 80% part because plant cell wall is made up of cellulose
Protein
Carbohydrates
Main
First
Ratio of H and O
So they are called
Main source of. Energy
Respiratory substrate
2: 1
Hydrates of carbon
Formula of carbohydrates
Sugars
Classification of carbohydrate. On basis of
Classified types
Cx(h2o)y
Simple carbohydrates which are soluble in water and sweet in taste
Monosaccharides obtained on hydrolysis
As monosaccharides, oligosaccharides, polysaccharides
Monosaccharides
In general formula
All monosaccharide occurs in
Except
Structure
Simplest sugars which cannot be further hydrolysed
X is almost equal to y i.e no. Of carbon and oxygen atom are same
All monosa. Occur in d and l form
Dihydroxy acetone because chiral carbon is absent
Is either ring or straight chain
A six membered ring
A 5 membered ring
Anomers
Occur / exist
Pyranose [ 4C +1 O ]
Furanonse
Position of -H and -OH at C1
Cyclic form
Aqueous solution, glucose
Epimers
Exist
Mannose
Eg
Galactose
Also called as
Eg
Isomers formed as a result of interchange of - OH and -H on C-2,C-3,C-4 of glucose
In both linear & cyclic form
Difference on C2 carbon in glucose . Rarely occurs in free form
Present as component of some compounds e.g hemicellulose - wood
Difference on C4 carbon rarely occurs in free form
Occurs as compound of some compounds
Most abundant in brain and nervous tissue so called as brain sugar
Eg hemicellulose, lactose, pectin , glycolpid
Trioses
Formula
Eg
Tetroses
Formula
Eg
No of carbon = 3 simplest monosacc
C3H6O3
Digydroxy acetone , glyceraldehydrade
No of C =4
C4H8O4
Erythrose , Erythrulose
Pentose
Common formula
Ribose +nt
Deoxyribose +nt
No of C =5
C5H10O5
In RNA ATP FAD FMN NAD
In dna
C5H10O4
Hexoses
Formula
Eg
No of C = 6
C6H12O6
Mannose
Galactose
Glucose
Fructose
Glucose
Most
Also known as
-||||—
Main
It’s rotate in direction
Abundant organic compound on earth
More abundant in grapes so also known as grape sugar
More abundant in blood so known as blood sugar
Respiratory substance
It rotates Ppl in right direction
Fructose
More abundant
It rotates ppl
Heptoses
Formula
Eg
Sweetest carbohydrate
In honey and sweet fruits so also known fruit sugar
Levorotatory Ratates PPL in left direction
No of C=7 largest monosacc
C7H14O7
Sedoheptulose
Oligosaccharide are
Monosacc are linked
Elimination
Glycosidic linkage formed ( structure )
Are those carbohydrate which on hydrolysis yield 2 to 10 monosacc
Together by glycosidic bonds
One molecule of H2O
Always formed b/w ring structures of monsacc
Disaccharide are
Known as
Eg
Composed of two monosacc units
Sugar = all disaccharide are water soluble and sweet in taste
Sucrose,
Trehalose
Maltose
Lactose
Maltose
Commonly called
Monosaccharides unit
Glycosidic bond
Nature
Intermediate compound
More abundant
Malt sugar
Alpha-D- glucose + alpha -D- glucose
Alpha 1—> 4
Reducing
Of starch digestion
In germinating starchy seeds
Lactose is
Monosaccharides unit
Glycosidic bond
Nature
Is
Present
Milk sugar
Beta-D- galactose + beta - D- glucose
Beta 1—> 4 reducing
Least sweet sugar
+nt only in mammals milk
Sucrose also called as
Monosaccharides unit
Linkage
Nature
Present in
Cane sugar/ table sugar/common sugar/commercial sugar
Alpha-D-glucose ( pyronose ) + beta -D- fructose
1<—> 2
Non reducing
Transport if sugar through phloem mainly occurs in form of sucrose
Trehalose +nt
Monosaccharides unit
Glycosidic bond
Nature
In haemolymph of insects
Alpha-D-glucose + alpha -D- glucose
1<—> 1
Non reducing
Polysaccharides / glycans
Composed
Are ( in water, taste)
Are polymers
Nature
But in polysaccharides chain
Large no of monosaccharides unit
Insoluble in water and do not taste sweet
Polymer/macromolecule of monosaccharides (monomer)
Non reducing
Right end is reducing end
Left end is non reducing end
Glycans
Nutritive
Eg
Structural
+nt as stored food
Starch & glycogen
Used in structure formation
Eg cellulose & chitin
Homopolysaccharide composed
Eg
Of same monomers
Cellulose
Starch
Chitin
Glycogen
Inulin
Cellulose ( branched / unbranched )
Monomer
Glycosidic bond
Unit
Main component
Wood
Cotton
Most abundant
Unbranched
Beta -D- glucose
Beta 1—> 4
Units ( 6000 to 10000)
Main component of plant cell wall
50% cellulose
90% cellulose
Organic compound of plant kingdom
Cellulose also used
______ made from ____
Starch monomer unit
Glycosidic
Main
In potato amylose
Amylopectin
To form Rayon fibre ( artificial silk)
Paper made up from plant pulp is cellulose
Alpha-D- glucose
Alpha1 →4 and alpha l -6
Stared food in plant
20%
80%
Starch iodine solution
Unbranched chain = units
Linkage
Branched chain = units
Branching occurs
Linkage
branching points
Gives blue colour
Amylose = 200 - 1000 alphaD glucose
Alpha 1 →4
Amylopectin = 6000 - 37000 alpha D glucose
At 24-30 alpha - d - glucose
Alpha 1 →4 and 1→ 6
Alpha l →6