Keywords Flashcards
(28 cards)
Zwitterion
Molecular ion with both positive & negative charges but neutral overall
Dipeptide
Molecule made up of two amino acids joined by peptide bonds
Primary structure
Sequence of amino acids in a polypeptide chain
Secondary structure
alpha-helix or beta-pleated structure formed by hydrogen bonding
Tertiary structure
3D shape of the protein formed by more hydrogen, ionic bonds and disulfide bridges
How are disulfide bridges formed
Oxidation between two cysteine amino acids
R-S-H on both undergo oxidation reactions to eliminate the 2H+ and 2e- to form R-S-S-R
How are ionic bonds formed
Zwitterions in amino acids - COOH group protonates the NH2 group by donating a H+ to form H3N+—CHR—COO-
Ionic bond occurs between the oppositely charged ends of two zwitterions
Complementary definition
Adenine binds to Thymine
Cytosine binds to Guanine
Nucleotide definition
Molecule formed from a phophate, pentose sugar (2-deoxyribose) and a nitrogen containing base
From a condensation reaction
Active site definition
Part of the enzyme where a substrate binds.
Specific structure so only complementary structure substrate can bind
Functional groups definition
Specific atom/ group of atoms which give certain chemical and physical properties
Homologous series definition
Same functional group but different length of carbon chain.
General formula
Formula shows the number of atoms of each element in a substance with n carbon atoms
Molecular formula
Formula shows the actual number of atoms of each element in a compound
Empirical formula
Formula shows simplest whole number ratio of atoms of each element in a compound
Displayed formula
Formula shows every atom and bond in the molecule
Structural formula
Formula shows how the atoms are joined together in a molecule
Can be used to draw a molecule
Skeletal formula
Formula where corners of lines represent CH2 unit
Structural isomerism
Same molecular formula but different structural formula
Stereoisomerism
Same structural formula but different arrangement of atoms in space
Chain isomerism
Same molecular formula, different carbon chain length
Position isomerism
Same molecular formula and carbon chain length, position of functional group on carbon chain is different