Kinetics Flashcards

1
Q

define activation energy

A

Minimum amount of energy required for a reaction to occur

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2
Q

what must happen for a reaction to occur

A
  • particles must collide w E>Ea
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3
Q

Why might a reaction occur very slowly?

A
  • A small number of particles have E≥Ea
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4
Q

If a reaction occurs very slowly because only a small number of particles have E≥Ea, why will all of the reactants eventually gain enough energy to react?

A
  • Molecules gain energy
  • Due to collisions
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5
Q

Why do some particles only have a very small amount of energy?

A
  • Collisions
  • Cause some molecules to slow down or lose energy
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6
Q

What is the rate of reaction?

A
  • rate of change in concentration / per unit of time
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7
Q

affect of temperature increase on rate

A
  • More particles have E≥Ea
  • Increases frequency of successful collisions
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8
Q

affect of concentration increase on rate

A
  • Increase in number of particles per unit volume
  • Increases frequency of successful collisions
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9
Q

affect of pressure increase on rate

A
  • Increase in number of particles per unit volume
  • Increases frequency of successful collisions
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10
Q

When drawing the curve for a higher temperature:

A
  • The High T peak must be further to the right
  • The curves must only cross once
  • High T curve is wider/broader
  • The size of the shaded area is larger for High T
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