Kinetics Flashcards
(44 cards)
What does the term rate describe in chemical reactions?
The speed of a reaction
How is the rate of reaction defined?
The change in concentration of a reactant or product in a given time
What is the formula to calculate the rate of reaction?
Rate = Change in concentration / Time
What are the units for measuring rate of reaction?
mole dma = mol dma s
What happens to the rate of reaction as reactants are used up?
The rate decreases
When does a reaction stop?
When one of the reactants is used up
What is the rate of reaction when it stops?
0
What theory explains how reacting molecules collide leading to a reaction?
Collision theory
What must occur for a reaction to take place during a collision?
The conditions must be right
What is activation energy?
The energy needed to break the initial bonds during a collision
What type of collision is more likely to result in a reaction?
Head-on collision
What happens during a glancing blow collision?
No reaction occurs
What occurs if the collision energy is less than the activation energy?
The molecules just bounce apart
What must the orientation of molecules be for products to be made?
Correct orientation
Fill in the blank: The rate of reaction is highest when the concentrations of the reactants are at their _______.
highest
What is the effect of temperature on the rate of a chemical reaction?
An increase in temperature will increase the rate of reaction
Higher temperature leads to faster molecular movement, more collisions, and a greater proportion of molecules exceeding the activation energy.
How does increased temperature affect molecular movement?
Molecules move faster and have more energy
This increased movement contributes to a higher reaction rate.
What happens to the number of collisions per unit time when temperature increases?
There are more collisions per unit time
More collisions increase the probability of successful reactions.
What is activation energy in the context of chemical reactions?
The minimum energy that reactants must possess for a successful collision
Molecules need energy greater than activation energy to react.
Fill in the blank: A greater number of molecules have an energy which is greater than the _______.
activation energy
This contributes to more successful collisions per unit time.
What is the relationship between successful collisions and reaction rate?
More successful collisions per unit time lead to an increased reaction rate
Successful collisions are necessary for a reaction to occur.
How does higher pressure affect the rate of a reaction?
Higher pressure increases the rate of a reaction
This is because higher pressure decreases the volume, increasing the concentration of gaseous molecules.
What happens to the volume when pressure is increased?
The volume decreases
This is a direct result of applying higher pressure in a gaseous system.
What effect does increasing pressure have on the number of particles per volume?
It increases the number of particles per volume
More particles in a given volume lead to a higher likelihood of collisions.