Kinetics Flashcards

(44 cards)

1
Q

What does the term rate describe in chemical reactions?

A

The speed of a reaction

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2
Q

How is the rate of reaction defined?

A

The change in concentration of a reactant or product in a given time

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3
Q

What is the formula to calculate the rate of reaction?

A

Rate = Change in concentration / Time

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4
Q

What are the units for measuring rate of reaction?

A

mole dma = mol dma s

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5
Q

What happens to the rate of reaction as reactants are used up?

A

The rate decreases

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6
Q

When does a reaction stop?

A

When one of the reactants is used up

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7
Q

What is the rate of reaction when it stops?

A

0

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8
Q

What theory explains how reacting molecules collide leading to a reaction?

A

Collision theory

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9
Q

What must occur for a reaction to take place during a collision?

A

The conditions must be right

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10
Q

What is activation energy?

A

The energy needed to break the initial bonds during a collision

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11
Q

What type of collision is more likely to result in a reaction?

A

Head-on collision

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12
Q

What happens during a glancing blow collision?

A

No reaction occurs

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13
Q

What occurs if the collision energy is less than the activation energy?

A

The molecules just bounce apart

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14
Q

What must the orientation of molecules be for products to be made?

A

Correct orientation

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15
Q

Fill in the blank: The rate of reaction is highest when the concentrations of the reactants are at their _______.

A

highest

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16
Q

What is the effect of temperature on the rate of a chemical reaction?

A

An increase in temperature will increase the rate of reaction

Higher temperature leads to faster molecular movement, more collisions, and a greater proportion of molecules exceeding the activation energy.

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17
Q

How does increased temperature affect molecular movement?

A

Molecules move faster and have more energy

This increased movement contributes to a higher reaction rate.

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18
Q

What happens to the number of collisions per unit time when temperature increases?

A

There are more collisions per unit time

More collisions increase the probability of successful reactions.

19
Q

What is activation energy in the context of chemical reactions?

A

The minimum energy that reactants must possess for a successful collision

Molecules need energy greater than activation energy to react.

20
Q

Fill in the blank: A greater number of molecules have an energy which is greater than the _______.

A

activation energy

This contributes to more successful collisions per unit time.

21
Q

What is the relationship between successful collisions and reaction rate?

A

More successful collisions per unit time lead to an increased reaction rate

Successful collisions are necessary for a reaction to occur.

22
Q

How does higher pressure affect the rate of a reaction?

A

Higher pressure increases the rate of a reaction

This is because higher pressure decreases the volume, increasing the concentration of gaseous molecules.

23
Q

What happens to the volume when pressure is increased?

A

The volume decreases

This is a direct result of applying higher pressure in a gaseous system.

24
Q

What effect does increasing pressure have on the number of particles per volume?

A

It increases the number of particles per volume

More particles in a given volume lead to a higher likelihood of collisions.

25
True or False: Increasing pressure allows molecules more space to move around.
False ## Footnote Higher pressure reduces the space available for molecular movement.
26
Fill in the blank: Increasing pressure leads to an _______ in the concentration of gaseous molecules.
increase ## Footnote This is due to the decrease in volume associated with higher pressure.
27
What is the relationship between pressure and collision frequency?
Higher pressure increases collision frequency ## Footnote With less space to move, molecules are more likely to collide.
28
What happens to the rate of a reaction when the collision frequency increases?
The rate of the reaction increases ## Footnote More collisions occur with energy greater than or equal to the activation energy.
29
How does an increase in concentration affect the rate of reaction?
It increases the rate of reaction ## Footnote More molecules lead to more collisions.
30
What is the effect of increasing the number of particles per volume?
It increases the collision frequency ## Footnote More collisions result in a higher reaction rate.
31
What does an increase in surface area do to the rate of reaction?
It increases the rate of reaction ## Footnote A decrease in particle size exposes more particles to collide.
32
What is the relationship between surface area and collision frequency?
An increase in surface area leads to an increase in collision frequency ## Footnote More exposed particles are available to collide.
33
Fill in the blank: An increase in _______ will increase the rate of reaction.
concentration
34
True or False: A decrease in particle size will decrease the rate of reaction.
False ## Footnote A decrease in particle size increases surface area, leading to more collisions.
35
What does an increase in the number of collisions with energy greater than or equal to the activation energy result in?
An increase in the rate of reaction
36
How does temperature affect the rate of a chemical reaction
37
How does pressure increase the rate of a reaction
… increase in the collision theory Increases the rate of reaction
38
How does concentration affect the rate of reaction
39
How does surface area affect the rate of reaction
40
How does a catalyst affect the rate of reaction
A catalyst provides an alternative route for the reaction with a lower activation energy
41
The Boltzmann distribution
42
Boltzmann graph
43
Effect of temperature on reaction rate. Boltzmann graph
44
Effect of a catalyst on reaction rate. Boltzmann