lattice enthalpy Flashcards
enthalpy of formation
The enthalpy change that takes place when one mole of a compound is formed from its elements under standard conditions, with all reactants and products in their standard states.
What type of reaction is enthalpy of formation?
exothermic
first ionisation energy
the enthalpy change required to remove one electron from each atom in one mole of gaseous atoms to form one mole of gaseous 1+ ions
what type of reaction is first ionisation energy
endothermic
second ionisation energy
the energy required to remove one electron from each ion in one mole of gaseous 1+ ions of an element to form one mole of gaseous 2+ ions
what type of reaction is second ionisation energy?
endothermic as energy is required to overcome attraction between negative electron and positive nucleus
first electron affinity
the enthalpy change that takes place when when one electron is added to each atom in one mole of gaseous atoms to form one mole of gaseous 1- ions
what type of reaction is first electron affinity?
exothermic as the electron being added is attracted in towards the nucleus
second electron affinity
enthalpy change that takes place when one electron is added to each ion in one mole of gaseous 1- ions to form one mole of gaseous 2- ions
lattice enthalpy
the enthalpy change that accompanies the formation of one mole of an ionic compound from its gaseous ions under standard conditions
what reaction is lattice enthalpy
exothermic
enthalpy of atomisation
the enthalpy change that takes place when one mole of gaseous atoms is formed from an element in its standard state
The first ionisation energy of sodium is more endothermic than that of potassium. Explain why.
Sodium - atomic radius is smaller
- so nuclear attraction increases.
The lattice enthalpy of sodium oxide is more exothermic than that of potassium oxide. Explain why.
Na+ is smaller so Na+ has stronger attraction to O2-
Enthalpy of hydration.
Enthalpy change when one mole of hydrated/ aqueous ions are formed.
Gaseous ions dissolve in water.
Enthalpy of solution
Enthalpy change for one mole of a compound/ substance/ solid dissolving in water.