lattice enthalpy Flashcards

1
Q

enthalpy of formation

A

The enthalpy change that takes place when one mole of a compound is formed from its elements under standard conditions, with all reactants and products in their standard states.

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2
Q

What type of reaction is enthalpy of formation?

A

exothermic

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3
Q

first ionisation energy

A

the enthalpy change required to remove one electron from each atom in one mole of gaseous atoms to form one mole of gaseous 1+ ions

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4
Q

what type of reaction is first ionisation energy

A

endothermic

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5
Q

second ionisation energy

A

the energy required to remove one electron from each ion in one mole of gaseous 1+ ions of an element to form one mole of gaseous 2+ ions

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6
Q

what type of reaction is second ionisation energy?

A

endothermic as energy is required to overcome attraction between negative electron and positive nucleus

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7
Q

first electron affinity

A

the enthalpy change that takes place when when one electron is added to each atom in one mole of gaseous atoms to form one mole of gaseous 1- ions

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8
Q

what type of reaction is first electron affinity?

A

exothermic as the electron being added is attracted in towards the nucleus

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9
Q

second electron affinity

A

enthalpy change that takes place when one electron is added to each ion in one mole of gaseous 1- ions to form one mole of gaseous 2- ions

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10
Q

lattice enthalpy

A

the enthalpy change that accompanies the formation of one mole of an ionic compound from its gaseous ions under standard conditions

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11
Q

what reaction is lattice enthalpy

A

exothermic

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12
Q

enthalpy of atomisation

A

the enthalpy change that takes place when one mole of gaseous atoms is formed from an element in its standard state

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13
Q

The first ionisation energy of sodium is more endothermic than that of potassium. Explain why.

A

Sodium - atomic radius is smaller
- so nuclear attraction increases.

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14
Q

The lattice enthalpy of sodium oxide is more exothermic than that of potassium oxide. Explain why.

A

Na+ is smaller so Na+ has stronger attraction to O2-

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15
Q

Enthalpy of hydration.

A

Enthalpy change when one mole of hydrated/ aqueous ions are formed.
Gaseous ions dissolve in water.

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16
Q

Enthalpy of solution

A

Enthalpy change for one mole of a compound/ substance/ solid dissolving in water.