Lipids Flashcards
(32 cards)
lipids have a low solubility in ??? and are relatively hydrophobic
water
phospholipids are structural elements of membranes or energy storage?
structural elements
fats/oils/triacylglycerides are structural elements of membranes or energy storage?
energy storage
Fatty acid general structure is CH3–(CH2)n—COOH with COO- at a pH of ???
7
saturated fatty acids contain how many double bonds between carbons?
no double bonds
monounsaturated fatty acids contain how many double bonds between carbons?
1
polyunsaturated fatty acids contain how many double bonds between carbons?
more than 1 in the alkyl chain
saturated fatty acids pack in a fairly ??? way due to extensive favourable interactions
orderly way
unsaturated FAs don’t pack very well because they are ??? by the double bond = less favourable interactions
kinked
TRUE or FALSE: less energy is required to disrupt the order of unsaturated FAs
TRUE
TRANS-fatty acids form by partial ??? of unsaturated FAs
dehydration
trans FAs can pack more regularly and have higher ??? than CIS form
melting point
TRUE or FALSE: solubility decreases as chain length increases
TRUE
Melting point decreases as chain length ??? and as number of double bond increases
decreases
Branched-chain FAs increase the fluidity of membranes because they ??? extent of membrane-lipid packing
decrease
cis double bond decreases the melting point- yes or no
yes
Triacylglycerols are a derivative of ??? where the carboxylic acid group from a FA esterifies with each OH group on glycerol
glycerol
Phospholipids:
glycerophospholipid (phosphoglycerides) have a ??? backbone and comprise about 2/3 of membrane phospholipids
glycerol backbone
Glycerophospholipid: 2 FAs esterify with the 1st and 2nd OH group of ??? whilst the phosphate group is attracted to the 3rd Carbon
glycerol
TRUE or FALSE: the highly polar phosphate group on a glycerophospholipid can be further esterified by an alcohol head group eg phosphatidylcholine
TRUE
Phsopholipid:
Sphingolipids have a ??? backbone, are less abundant with only 1/3
sphingosine
sphingolipids:
sphingosine ??? has a cis-hydrocarbon chain side group at C3 and an amide-linked fatty acid
backbone
sphingomyelin is an example of a ??? in membrane phospholipids
sphingolipid
Glycolipids (glycosphingolipids) have a sphingosine ??? and a direct glycosidic linkage between the head (the sugar/mono/oligosaccharide) and backbone. the sugar group increases ???
backbone
polarity