macromolecules Flashcards

(39 cards)

1
Q

5 ways the carbon backbone can vary

A

Length (number of carbons)
Branching
Number of double bonds
Circularization
Isomerization

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

what’s is the Max H that 2 C’s can hold. what happens if a compound holds less than this

A

6
means its unsaturated

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

what’s unsaturated

A

carbon backbone with not the max number of H’s bonded
- DOUBLE BONDS SHOW THIS

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

what’s saturated

A

carbon backbone with the max number of H’s bonded

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

isomerization meaning

A

Things with identical chemical formulas but different structures

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

3 ways isomers can vary in structure

A

-Structural
-Geometric
-Enantiomers

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

what does Cis and Trans mean in geometric isomer variation

A
  • Cis = X on the same side of the horizontal line – no rotation around that bond
  • Trans - X on opposite side of the horizontal line – allow rotation around that bond
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Enantiomers variation in isomers

A

structure is mirrored

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

4 Biological macromolecules

A

Carbohydrates
Fats
Proteins
Nucleic acids

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

reaction that brings monomers together

A

dehydration synthesis (lose water)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

reaction that breaks monomers apart

A

hydrolysis (add water)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

carbohydrates / sugar monomers, polymers and type of bond

A

Monosaccharides - CH2O (generally)
Polysaccharides
Glycosidic linkages

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Lipid monomers, polymers and type of bond

A

Fatty acids
Triacylglycerols
Ester linkages

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Proteins monomers, polymers and type of bond

A

Amino acids
Polypeptides
Peptide bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Nucleic acid monomers, polymers and type of bond

A

Nucleotides
Polynucleotides
Phosphodiester bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

what are carbohydrates classified by

A

location of the carbonyl – tells you if it’s an ALDOSE or KETOSE

17
Q

3 things carbohydrates are classified by

A
  • location of the carbonyl (aldose or ketose)
  • number of carbons (length of chain)
  • spatial arrangement e.g. alpha or beta glucose
18
Q

location of carbonyl on aldose and ketose carbohydrates

A

Aldose = carbonyl on end (top or bottom) ^
Ketose = carbonyl in middle <

19
Q

Monosaccharides importance in cells

A

serves as fuel source

20
Q

what are Disaccharides

A

2 monos joined by a dehydration synthesis

21
Q

3 types of disaccharides

A
  • Maltose = glucose + glucose
  • Sucrose (poison) = glucose + fructose
  • lactose = galactose + glucose
22
Q

what are Polysaccharides

A

polymers of sugar

23
Q

2 types of polysaccharides

A
  • Starch & glycogen
  • cellulose
24
Q

Starch & glycogen characteristics

A
  • Store energy
    S = plant
    G = animals
  • Alpha glucose monomer (OH on bottom)
  • Helicase shape
  • human digestible
25
cellulose characteristics
- Provides structure to plants / involved in fibre - Beta glucose monomer (OH on top) - Linear sheets shape - not human digestible
26
difference between alpha and beta glucose polymers
- alpha glucose polymers spiral and form helix - beta glucose polymers impossible to spiral (linear) but create strong fibres by lining up by hydroxyl groups
27
3 types of lipids
Fats Phospholipids Steroids
28
lipids characteristic
- oils - non polar
29
fats major function
energy storage
30
what 2 smaller molecules are fats Constructed from
Fatty acids (3) Glycerol (1)
31
2 things Fatty acids vary in
length of carbon chain degree of saturation
32
what are Saturated fatty acids
- maximum number of H - no double bonds (means there is free rotation aka TRANS) – allows them to come together and nest to hide from water - solid at room temp (all animal fats except fish are saturated)
33
what are unsaturated fatty acids
- missing amount of H bonds - 1 or more double bonds - causes a kink (no free rotation around the bond aka CIS) - molecules cannot stack on one another - liquids at room temp (fat of plants and fish)
34
what are phospholipids constructed from
2 fatty acids Phosphate group Glycerol
35
important characteristic of phospholipids
Hydrophobic tail Hydrophilic head (phosphate group)
36
Major role of phospholipids
cell membrane - When put into water they self-assemble into a phospholipid bilayer - Hydrophilic head on outside + Hydrophobic tail on inside
37
Steroids structure
Carbon skeleton of 4 rings (3 x 6sided and 1 x 5sided) - see notes for drawing
38
most common steroid and its 2 important roles
cholesterol - Important component of lipid bilayers - Precursor for signalling molecules
39
where is cholesterol synthesised
liver