Module 2 Flashcards

(72 cards)

1
Q

What are isotopes?

A

atoms of the same element with different numbers of neutrons and different masses

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2
Q

What is relative isotopic mass?

A

the mass of an atom of an isotope compared to 1/12th of the mass of an atom of carbon-12

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3
Q

What is relative atomic mass?

A

the weighted mean mass of an atom of an element compared to 1/12th of the mass of an atom of carbon-12

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4
Q

What is the mass number?

A

the number of protons and neutrons in the nucleus; always the biggest number

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5
Q

What is the atomic number?

A

the number of protons

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6
Q

What are ions?

A

atoms that have lost or gained electrons

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7
Q

How do you calculate relative atomic mass?

A

(abundance A x m/z A) + (abundance B x m/z B) / total abundance OR 100 (if % abundance given)

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8
Q

What are some complex ions?

A

OH⁻ (hydroxide)
NO₃⁻ (nitrate)
NH₄⁺ (ammonium)
SO₄²- (sulphate)
CO₃²- (carbonate)
Ag+ (silver)
Zn²⁺ (zinc)

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9
Q

What are spectator ions?

A

ions which aren’t involved in the reaction; they are cancelled out in simplest ionic equations

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10
Q

How to work out moles in solids?

A

n = mass / Mr
mass in grams

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11
Q

How to work out moles in liquids?

A

n = v x c
volume in dm3
concentration in moldm-3

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12
Q

How do you convert from cm3 to dm3 to m3?

A

cm3 to dm3: divide by 1000
dm3 to m3: divide by 1000
cm3 to m3: divide by 1000000

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13
Q

How to work out moles in gases?

A

n = v / 24dm3

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14
Q

What is the ideal gas equation?

A

pV = nRT
pressure in Pa
volume in m3
R (gas constant) is 8.31 JK-1mol-1
temperature in K

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15
Q

What are the standard conditions?

A

`298K
100kPa

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16
Q

What is the empirical formula?

A

the simplest whole number ratio of elements in a compound

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17
Q

How to work out percentage yield?

A

(actual yield / theoretical yield) x 100

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18
Q

How to work out atom economy?

A

(Mr of desired product / Mr of all products) x 100
balance equation and use big numbers when calculating moles

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19
Q

What are acids?

A

proton donors; donate H+ ions which are just protons

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20
Q

What are bases?

A

proton acceptors

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21
Q

What is an alkali?

A

a soluble base; produce OH- ions

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22
Q

What is a weak acid?

A

acids which partially dissociate in solution

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23
Q

What is a strong acid?

A

acids which fully dissociate in solution

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24
Q

What are polyprotic acids?

A

acids which can donate more than 1 proton
e.g. H2SO4 (diprotic) and H3PO4 (triprotic)

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25
What is the overall ionic equation for neutralisation?
H+ (aq) + OH- (aq) ⇌ H2O (l)
26
What is produced when a metal and acid react together?
a salt and hydrogen
27
What is produced when a metal oxide and acid react together?
a salt and water
28
What is produced when a metal hydroxide and acid react together?
a salt and water
29
What is produced when a metal carbonate and acid react together?
a salt, water and carbon dioxide
30
What are concordant results?
results within 0.10 cm3 of each other
31
How do you work out a titre?
titre = final volume - initial volume
32
What colours does the indicator phenolphthalein produce in acids and alkalis?
acids = colourless alkalis = pink
33
What colours does the indicator methyl orange produce in acids and alkalis?
acids = red alkalis = yellow
34
What is oxidation?
loss of electrons
35
What is reduction?
gain of electrons
36
What is a redox reaction?
reactions which involve both reduction and oxidation
37
What happens to reducing agents?
they lose electrons and so are oxidised themselves
38
What happens to oxidising agents?
they gain electrons and so are reduced themselves
39
What are the oxidation state rules?
- uncombined elements are always 0 - ions have the same charge as on the ion - group 1 is always +1 - group 2 is always +2 - aluminium is always +3 - hydrogen is +1 except in hydrides where it is -1 - chlorine is -1 except in compounds with F or O where it is +1 - fluorine is always -1 - oxygen is -2 except in peroxides where it is -1 and OF2 where it is +2
40
What are the 4 subshells?
s-subshell p-subshell d-subshell f-subshell
41
How many orbitals and therefore how many electrons can each subshell hold?
s-subshell: 1 orbital; holds 2 electrons p-subshell: 3 orbitals; holds 6 electrons d-subshell: 5 orbitals; holds 10 electrons f-subshell: 7 orbitals; holds 14 electrons
42
How many electrons can be held in shell 1?
2 electrons (1s)
43
How many electrons can be held in shell 2?
8 electrons (2s, 2p)
44
How many electrons can be held in shell 3?
18 electrons (3s, 3p, 3d)
45
How many electrons can be held in shell 4?
32 electrons (4s, 4p, 4d, 4f)
46
What shape is the s-orbital?
spherical; the 2 electrons can move anywhere within the sphere
47
What shape is the p-subshell?
3 orbitals in a dumbbell shape; each orbital holds 2 electrons that can move anywhere within the shape
48
What is spin pairing?
when 2 electrons occupy 1 orbital and they spin in opposite directions
49
What are the rules to electron configuration?
- fill 4s before 3d - place electrons singularly first then pair up (due to electron repulsion)
50
What are the 2 electron configuration anomalies?
- copper: fully fills 3d before 4s - chromium: singularly fills 3d before 4s
51
What is ionic bonding?
the electrostatic attraction between positive and negative ions
52
What structure do ionic compounds have?
giant ionic lattice structure
53
Do ionic compounds conduct electricity?
yes when molten or aqueous; the ions dissociate and so are free to move and carry a charge
54
Do ionic compounds dissolve in water?
yes; most do as water molecules are polar and so they attract the positive and negative ions
55
Do ionic compounds have high or low melting points?
high; there are many electrostatic forces between the oppositely charged ions so a lot of energy is required to overcome them
56
What is covalent bonding?
electrostatic attraction between a shared pair of electrons and the positive nuclei of the bonded atoms
57
What is a dative covalent/coordinate bond?
where 1 atom donates both electrons in a shared pair of electrons
58
What are the rules to the shape of molecules?
- bond pairs repel equally - lone pairs repel more than bond pairs - 2 lone pairs repel even further
59
What is the name and bond angle of molecules with 2 bond pairs?
linear; 180° e.g. BeCl2
60
What is the name and bond angle of molecules with 3 bond pairs?
trigonal planar; 120° e.g. BF3
61
What is the name and bond angle of molecules with 4 bond pairs?
tetrahedral; 109.5° e.g. CH4
62
What is the name and bond angle of molecules with 5 bond pairs?
trigonal bipyramidal; 90° and 120° e.g. PCl5
63
What is the name and bond angle of molecules with 6 bond pairs?
octahedral; 90° e.g. SF6
64
What is the name and bond angle of molecules with 3 bond pairs and 1 lone pair?
trigonal pyramidal; 107° e.g. NH3
65
What is the name and bond angle of molecules with 2 bond pairs and 2 lone pairs?
non-linear; 104.5° e.g. H2O
66
What is electronegativity?
the ability of an atom to attract electrons in a bonding pair to itself
67
What is the most electronegative element?
fluorine; the closer to fluorine the more electronegative an element is
68
What are induced dipole dipole forces also known as?
London forces
69
What are induced dipole dipole forces?
when electrons in a molecule/atom form a dipole when they move near to another atom/molecule the δ+ on 1 atom/molecule becomes attracted to a δ- on another atom/molecule creating a force of attraction; exist in all molecules/atoms regardless of polarity but only exist when 2 molecules/atoms are nearby
70
What are permanent dipole dipole forces?
when the δ+ of one molecule is attracted to the δ- on another molecule; only exists in molecules with a polarity and these interactions are permanent
71
What is hydrogen bonding?
occurs when hydrogen on 1 molecule forms a bond with the lone pair on nitrogen, oxygen or fluorine on another molecule
72
Name the three intermolecular forces in increasing strength.
induced dipole dipole, permanent dipole dipole, hydrogen bonding