Module 4 Flashcards

(63 cards)

1
Q

is typically defined as a nonmetallic construction material, which is able to bond substrates together by surface adhesion and internal cohesion

A

adhesive

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2
Q

categories of classifying adhesives

A

solidification method
polymer base type
chemical base
solvent type
application category

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3
Q

refers to a protein-based bonding substance obtained from animal hooves, bones, and skins

A

glue

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4
Q

modern formulations of glue are derived from

A

natural polymers such as starch or are based on synthetic polymer classes

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5
Q

a more technically correct term compared to gluing

A

adhesive bonding

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6
Q

refers to the attraction or bond of one material to another

A

adhesion

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7
Q

refers to the internal attraction or bond of a material’s molecules

A

cohesion

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8
Q

___ of an adhesive is related to its molecular polarity and determines how well it is attracted to a substrate surface

A

surface tension

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9
Q

affect machinability, how the adhesive flows out over the substrate & level of adhesive penetration into the substrate

A

viscosity

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10
Q

expresses as a percentage, refers to the actual amount of material left to form a bond after all solvents and carrier liquids have been removed

A

solids content or nonvolatile content

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11
Q

can be regarded as a pigmented adhesive

A

ink

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12
Q

adhesive bonds are the result of three phenomena:

A

mechanical bonds, micro-mechanical adhesion, and intermolecular interaction

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13
Q

proposes that fluid adhesive flows into tiny surface irregularities

A

mechanical adhesion theory

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14
Q

what happens to when the adhesive solidifies in mechanical adhesion theory

A

adhesive mechanically locks into the surface cavities and can no longer be pulled away without destroying the surface

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15
Q

theory that explains paper or wood bonding

A

mechanical adhesion theory

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16
Q

theory explaining glass, metal, and plastic bonding

A

specific adhesion theory

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17
Q

proposes that bonding takes place when minute regions of positive and negative charge are brought into intimate enough contact that they mutually attract one another

A

specific adhesion theory

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18
Q

the surface charges in the surface adhesion theory are primarily a result of

A

dipole interaction, hydrogen bonding, and Van der Waals’ forces

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19
Q

passes the substrate through a gas flame that has been adjusted to have excess air

A

flame treatment

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20
Q

surface of materials with low polarity can be increased by

A

chemically altering the surface using flame treatments, corona discharge, or chemical treatment

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21
Q

creates a similar highly reactive atmosphere (ozone) using a high-frequency, high-voltage charge to ionize the air in contact with the plastic

A

corona discharge

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22
Q

plastic films are usually treated with __________ since the application of direct flame would harm most films

A

corona discharge

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23
Q

flame or corona treatment: somewhat more durable

A

flame treatment

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24
Q

to achieve good bonding, the dyne level of a surface should be about ______

A

10 dynes/cm higher than the surface tension of the wetting liquid

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25
dyne level of a surface to ensure adequate bonding of the adhesive material
37 dynes/cm or higher
26
surface tension can be measured by
measuring contact angle of a drop if distilled water with the test surface
27
it has been established that an adhesive must be:
1. polar to form chemical bonds with the substrate 2. fluid so it can flow out and make intimate contact with (wet out) the substrate
28
solidification method: loss of water.
water-borne
29
common examples of water-borne adhesive
starch, dextrin, and casein
30
a special category of water-borne adhesives are the emulsion types typified by _______, usually a _________.
"white glue" usually a polyvinyl acetate emulsion
31
solidification method: loss of solvent
solvent-based
32
solidification method: loss of heat
hot melts
33
do not need a diluent or solvent that is removed during solidification
hot melts
34
are usually based on liquid pre-polymers or special monomers that can be polymerized to a solid after application
reactive adhesives
35
example of reactive adhesives
epoxies & polyesters
36
various ways of initiating chemical reactions
mixing of two components or a component and a catalyst, atmospheric oxygen, atmospheric moisture, heat, or UV radiation
37
these types of adhesives take a special position as they don't show a defined solidification process in physical or chemical hardening terms
pressure sensitive
38
a liquid physical mixture (suspension) of powdered thermoplastic (polyvinyl chloride or acrylic) polymer and plasticizer(s)
plastisol
39
is a naturally occurring vegetable polymer usually extracted from the seeds, pitch, and roots of corn, grains, or potatoes.
starch
40
is the largest single starch-based adhesive application
corrugated board manufacture
41
generally are roasted or converted starches which have been cleaved by acids and heat to create shorter molecules
dextrin
42
have high tackiness, high solids, fair to good adhesion and are fast-drying
dextrin adhesives
43
___ treatment of starch produces jelly gums
alkaline
44
are derived from the phosphoprotein in acidified milk
casein adhesives
45
have a unique property of having good cold-water resistance but of being rapidly hydrolyzed in aqueous caustic solutions
casein adhesives
46
a collagen derivative, very tacky, protein-based glue used occasionally for set-up boxes and tube winding
animal glue
47
are based on polymers such as polyvinyl acetates, acrylates, and maleates, which in themselves are not water soluble
synthetic emulsion adhesives
48
is the most common base resin used in formulating hot-melt adhesives
ethylene-vinyl acetate
49
is important for viscosity control and adjustment of open time and set speed
wax
50
improve hot tack and viscosity of the formulation
tackifier
51
are often used to characterize hot melts
ring & ball (R&B) softening points
52
is the temperature at which the hot melt softens enough for a metal ball of a specified size and mass to drop through it
R&B softening point
53
hot melts come in a variety of solid shapes:
slats, pillows, wafers, chips are the most common terms
54
these adhesives are used most often by converters in coating and laminating operations, particularly with plastic substrates
lacquer adhesives
55
are applied and immediately oven-dried to leave a pressure-sensitive surface to which the next laminate component is nipped
laminating lacquers
56
are mostly based on one of two elastomeric polymer classes:
acrylics and rubber/resin blends
57
means that the adhesive has a greater tendency to stick to itself rather than to other surfaces
co-adhesive
58
a type of co adhesive usually based on natural rubber latex
cold-seal adhesives
59
are similar to pressure-sensitive adhesive
co-adhesive or cold-seal adhesive
60
were originally developed for bonding plastic-based chocolate bar wraps, where chocolate's low melting point precludes heat sealing
cold seals
61
take the finished laminate supplied to them by the laminating company and convert it into a bag, pouch, wrap, or other type of package for their liquid or dry product
flexible laminating adhesives
62
used to bond two or more continuous webs together to form a laminate which is used by packagers to form packages for their products
flexible laminating adhesive
63