Module 6: Quantum Mechanics Flashcards

(54 cards)

1
Q

He extended the wave-particle duality of light that Einstein used to resolve the photoelectric-effect paradox to material particles

A

Louis de Broglie

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2
Q

he predicted that a particle should also exhibit the behavior of a wave

A

Louis de Broglie

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3
Q

Formula for de Broglie wavelength

A

λ = h / mV

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4
Q

Is de Broglie wavelength not a characteristic of particles?

A

No

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5
Q

two scientists that demonstrated experimentally that electrons can exhibit wavelike behavior

A

C.J. Davisson and L.H. Germer

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6
Q

Field of study that includes quantization of energy, wave-particle duality, and the Heisenberg uncertainty principle to describe matter

A

Quantum Mechanics

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7
Q

This principle states that it is fundamentally impossible to determine simultaneously and exactly both the momentum and the position of a particle

A

Heisenberg Uncertainty Principle

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8
Q

Unlike de Broglie who thought of the electron in terms of circular stationary waves, this person properly though in terms of three-dimensional stationary waves

A

Schrodinger

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9
Q

three-dimensional stationary waves that Schrodinger thought of

A

Wavefunction (ψ)

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10
Q

Who proposed the interpretation of wavefunction?

A

Max Born

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11
Q

he said that electrons are still particles and so the waves represented by ψ are not physical waves but are complex probability amplitudes

A

Max Born

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12
Q

the square of this describes the probability of the quantum particle being present near a certain location in space

A

Wavefunction (ψ)

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13
Q

It can be used to determine the distribution of the electron’s density

A

Wavefunction (ψ)

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14
Q

This describe the location or general description of an electron

A

Quantum numbers

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15
Q

A general region in an atom within which an electron is most probable to reside

A

Atomic orbital

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16
Q

The four quantum numbers

A

principal
angular momentum
magnetic
spin

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17
Q

this quantum number specify the shell an electron occupies in an atom

A

Principal quantum number (n)

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18
Q

this quantum number defines the location of the energy level and general size and energy of the orbital

A

Principal quantum number (n)

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19
Q

this quantum number determines the average distance form nucleus

A

Principal quantum number (n)

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20
Q

This quantum number’s values are 1, 2, 3, 4, ..

A

Principal quantum number (n)

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21
Q

As the principal quantum number (n), what happens to the distance from the nucleus and energy?

A

Increases

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22
Q

This quantum number defines the shape of the orbital which is dependent on where you can probably find electrons

A

Angular Momentum Quantum Number (l)

23
Q

This quantum number is also known as the subshell

A

Angular Momentum Quantum Number (l)

24
Q

This quantum number’s values are 0, 1, 2, (n-1)

A

Angular Momentum Quantum Number (l)

25
This quantum number describes the orientation of the orbital in space
Magnetic Quantum Number (ml)
26
This quantum indicates the region that an electron occupies within a subshell based on the shape of the subshell
Magnetic Quantum Number (ml)
27
This quantum number's values are 0, +1, -1, +2, -2, (-l to +l)
Magnetic Quantum Number (ml)
28
This quantum number describes the orientation of electron spin
Spin Quantum Number (s)
29
A completely quantum phenomenon with no analogous in the classic al realm
Electron spin
30
Describes an intrinsic electron "rotating" or "spinning"
Electron Spin
31
This quantum number states that each electron acts as atiny magnet with an angular momentum, even though this rotation cannot be observed in terms of the spatial coordinates
Spin Quantum Number (s)
32
This quantum number's values are either +1/2 or -1/2
Spin Quantum Number (s)
33
Value of spin quantum number (s) with a slightly higher energy in an external field than the other
s = -1/2
34
Principle that states no two electrons in the same atom can have exactly the same set of all the four quantum number
Pauli Exclusion Principle
35
Which orbital have the lowest energy
Orbitals closest to the nucleus of an atom
36
lowest to highest energy of subshells
s < p < d < f
37
This is the arrangement of electrons in the orbitals of an atom
Electron Configuration
38
Three information that an electron configuration have
Principal quantum number (n) Orbital type (subshell ,l) number of electrons in a particular subshell
39
unpaired electrons that behave like a magnet and attract others
Paramagnetic
40
Principle that states that the procedure in which the electron configuration of the elements is determined by "building" them in order of atomic number
Aufbau Principle
41
Principle that states that lowest energy level should be filled up first before the higher energy levels
Aufbau Principle
42
writing the electron configuration by abbreviation using the noble gas closest to the atom
Abbreviated Electron Configuration
43
the electron occupying the inner shell orbitals
Core Electrons
44
outer-shell electrons
Valence Electrons
45
type of electrons that correspond to noble gases electron configuration
Core Electrons
46
type of electrons that heavily contribute to an element's properties and they are the electrons involved in chemical bonding
Valence Electrons
47
pictorial representations of the electron configuration, showing the individual orbitals and the pairing arrangement of electrons
Orbital diagrams
48
Electron configuration that is exceptions to the order of filling of orbitals that are indicated by Aufbau principle
Anomalous Electron Configuration
49
for this type of electron configuration, half-filled and completely-filled subshells apparently represent conditions of preferred stability
Anomalous Electron Configuration
50
electron configuration exceptions because the magnitude of the repulsion between electrons is greater than the differences in energy between subshells
Anomalous Electron Configuration
51
meaning of s, p, d and f?
sharp principal diffused fundamental
52
formula for number of orbitals in a subshell
2l + 1
53
formula for total number of orbital
n e2 (n squared)
54
formula for maximum number of electrons
2n e2 ( 2 n squared)