Octane Number Flashcards Preview

Chemistry: 21 - Fuels and Heats of Reactions > Octane Number > Flashcards

Flashcards in Octane Number Deck (21)
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1
Q

What produces the power needed to move the wheels of a car?

A

In the internal combustion engine of a motor car the power to turn the wheels in produced in the cylinders by the explosive reaction between petrol and air

2
Q

What does the smooth running of a car engine depend on?

A

The explosion between petrol and air occurring in the cylinder at exactly the right moment

3
Q

What happens if the explosion between petrol and air occurs to quickly in an engine?

A

Knocking occurs which is where the pistons vibrate and a metallic noise is heard from the engine

4
Q

What causes knocking?

A

An early explosion due to the petrol-air mixture exploding as it is compressed instead of the explosion being caused by the spark

5
Q

What effect does knocking have on the engine?

A

The engine loses power and the inside of the cylinders can be damaged

6
Q

Define auto-ignition

A

The premature ignition of the petrol-air mixture before ignition of the mixture by a spark takes place

7
Q

What type of hydrocarbons cause autoignition frequently?

A

Straight-chained alkanes such as heptane, octane and nonane

8
Q

What type of hydrocarbons didn’t cause autoignition frequently?

A

Branched-chain alkanes such as 2,2,4-trimethylpentane

9
Q

Why does petrol contain large amount of branched-alkanes?

A

As they don’t auto-ignite and are therefore more efficient than those that contain straight-chained molecules

10
Q

Define octane number

A

The octane number of a fuel is a measure of the tendency of the fuel to resist knocking

11
Q

What octane number is 2,2,4 trimethylpentane assigned?

A

An octane number of 100

12
Q

What is the structure for 2,2,4 trimethylpentane?

4

A

A chain of five carbons bonded together with single bonds

A methyl group on either side of the second carbon counting from the left to right

A methyl group on the top side of the fourth carbon counting from the left to the right

Hydrogens bonded to each carbon where there is already a methyl group

13
Q

What is 2,2,4 trimethylpentane also called?

A

Iso-octane

14
Q

What octane number is heptane assigned?

A

0

15
Q

In relation to assigning octane numbers to other hydrocarbons, what is the role of 2,2,4 trimethylpentane and heptane?

A

These are reference hydrocarbons

16
Q

How is the octane number of a fuel measured?

A

By comparing its performance with known mixtures of heptane and 2,2,4 trimethylpentane in a test engine

17
Q

Explain what is meant by an octane number of 97

A

This means that the fuels works as well as a mixture of 97% 2,2,4 trimethylpentane and 3% heptane

18
Q

List the three factors which affect octane number

A

Length of alkane chain

Degree of branching

Straight or cyclic structure

19
Q

What effect do different lengths of alkane chains have on octane number?

A

The shorter the alkane chain, the higher the octane number

20
Q

What effect does the degree of branching have on octane number?

A

The more branched the chain, the higher the octane number which is why 2,2,4 trimethylpentane has such a high octane number as it has three methyl branches

21
Q

What effect does having a straight or cyclic structure have on octane number?

A

Cyclic structures have a higher octane number than straight chain compound e.g hexane has an octane number of 25 but cyclohexane has an octane number of 83