Operators, Expectation Values and Uncertainties Flashcards

(57 cards)

1
Q

What are the Hamiltonian, Momentum and Spatial operators?

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2
Q

To determine the effect of one operator, or multiple operators, what do you do?

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You apply the operators to a test function f(x)

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3
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4
Q
A

Lct:11 for more processed steps

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5
Q
A

The eigenvalue can take ANY value for a momentum eigenstate- momentum is continuous, not quantised, unlike energy.

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6
Q

INFO: Just take the solution as it is, do not need to prove that u(x) is delta function.

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7
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8
Q

What is Postulate 2?

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9
Q

N2K

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Let u(x) = v(x) + w(x)

No, A is not a linear operator

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10
Q

N2K What is the property of the Hermitian operator? State in Bra-ket and integral form.

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11
Q

N2K Why must observables correspond to Hermitian Operators?

A

The eigenvalues of Hermitian operators are real, hence are observable - why they represent experimental observables.
The eigenvectors of Hermitian operators form an orthogonal basis

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12
Q

Hint: Use two generic functions f(x) + g(x)

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13
Q

Hint: Use two arbitrary functions f(x), g(x)

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14
Q
A

Units of energy = h(bar) * omega

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15
Q

State V(x) for a Quantum Harmonic Oscillator (QHO)

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16
Q

State the ladder operators of a QHO

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17
Q

What is the result of applying both ladder operators on each other? Rearrange for the Hamiltionian.

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18
Q

What is Postulate 3?

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19
Q

What does it mean if PSI(x) is already an eigenstate of the Operator?

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It means EVERY MEASUREMENT is known with complete certainty (does NOT CHANGE- SAME EIGENVALUE AND EIGENVECTOR).

This is called a determinant state

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20
Q

IMPORTANT: u2(x) is an eigenstate of the Hamiltonian, hence it is a determinant state, and all measurements will return the same value.

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21
Q

What happens if PSI(x) is not an eigenstate(i.e. a superposition of eigenstates)?

A

PSI(x) is not a determinant state, hence we can no know with certainty that every measurement will return the same value. It is likely a different eigenstate of the superposition (can only be the eigenstates of the superposition - all other amplitudes are 0) will be measured.

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22
Q

State the probability of obtaining the nth eigenstate upon measuring the observable of a superposition state. (Born’s Rule)

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23
Q
A

Normalise is the first step

24
Q

Important: Measuring observables with two operators of the SAME basis return eigenvalues(different) corresponding to the SAME eigenvector- will always measure same eigenstate.

The system is in a deteminant state. When the same eigenstate is returned for two operators, they are compatible.

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Important: Upon change of basis, all previous information on the state is lost, hence eigenstates can change.
27
State the commutation relation for compatible operators B and A.
Tells us associated observables are compatible
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In making a measurement we lose all information about the orginal state (as long as Psi in not already in an eigenstate i.e. is a superposition state). How do we get a picture of the origininal state? Take repeated measurements! What is the average of all measurements called?
The average of a set of repeated measurements of a Quantum state, not in an eigenstate is called the EXPECTATION VALUE. The image is more relevent to building up the orginal quantum state by taking many, many measurements.
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What is the equation for the expectation value in Bra-ket form?
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What is the expectation value equal to? (Sum form- find by using bra-ket notation with the sum notation of a quantum state) What does this sum represent?
The sum represents the average measurement O n weighted by its respective probability (P = Cn **2)
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You can use the known result for the Expectation value as shown, using cn**2 and On (the eigenvalue which is in this case = n) or do it the longer way round starting with which generates the same results.
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What is the uncertainty of an operator? (Give the equation of uncertainty)
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Hint: Consider the state Iv>
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What would a series of measurements of a sytem in an eigenstate be equal to? What is its uncertainty?
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What is the uncertainty for the following system not in an Eigenstate?
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State the generalised uncertainty principle
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Using the genralised uncertainty principle derive Heisenberg's Uncertainty Principle
41
What is Postulate 4? Hint: Time dependence and evolution of a system.
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What is the expression for the wavefunction of dependence in summation notation? Hint: The 'weighting' does change with time.
Since I un > has no explicit time dependence, Cn must be time dependent --> Cn(t) for PSI(x, t) to have explicit time dependence. un(x) is a time independent function/ket.
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Use the Postulate 4 to derive the full quantum state of the system. Hint: First find Cn(t) in terms of Cn(0), e^f(t). Postulate 4 in image if you do not remember.
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What is the TISE in ket notation?
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What is Cn(t)? Use Cn(t) to write the full quantum state in Ket notation.
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What is the full time-dependent quantum state for any Quantum State?
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Show that the epectation for the Hamiltonian is not time-dependent by acting on an eigenstate Iun>. Hint: For an eigenstate, Cn(0) = 1
- Write in time dependent form. - Find . The expectation value for the Hamiltonian is time independent, even though the state is.
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Show that the probabilty density of an energy eigenstate remains constant.
ONLY APPLIES TO ENERGY EIGENSTATES. Probability densities remain fixed in time.
50
Derive the expectation value of the Hamiltonian for time dependent superposition states. Compare the result to the expectation value of the Hamiltonian of superposition states with no time dependence. Start with psi given in image.
Time dependence does not effect the Hamiltonian. The expectation value of the Hamiltonian is totally time independent and has 0 time evolution. Same result.
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Which expectation values are time independent for stationary states?
Position, Momentum and Hamiltonian expectation values are time independent for stationary states.
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What is the Bra of Postulate 4? When is this used?
This is used in finding if an operator/measurement has time dependence.
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Test whether an arbitrary Operator, O's expectation value is time dependent. Hint: Expectation, d/dt, 4th postulate.
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Find the Ehrenfrest theorem for a general operator O. You may find the image attached useful.
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When is the expectation value of an operator time independent?
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